WO3/Pt photocatalyst supported by a ceramic filter for indoor air purification under visible light irradiation†

IF 3.5 Q3 ENGINEERING, ENVIRONMENTAL Environmental science. Advances Pub Date : 2024-10-08 DOI:10.1039/D4VA00188E
Sudipto Pal, Amruth Kaitheri, Sanosh Kunjalukkal Padmanabhan, Massimo Catalano, Stefano Perboni and Antonio Licciulli
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Abstract

Household air pollution exposure can lead to various diseases, including stroke, ischaemic heart disease, chronic obstructive pulmonary disease (COPD), and lung cancer. In this study, an indoor air purification technique was developed employing a visible light-activated photocatalyst consisting of a WO3/Pt-coated ceramic foam filter (CFF). Under visible light irradiation, the coated porous filter was able to decompose toluene, a prevalent indoor air contaminant. The interconnected three-dimensional structure of the CFF with open pores facilitated toluene adsorption and simultaneous decomposition by the photocatalyst. XRD analysis revealed that WO3/Pt had tungsten oxide in a monoclinic crystal structure with immiscible platinum metal clusters. The specific surface area and pore diameter were analyzed using the BET method, while the energy band gap was determined using DRS. XRF spectroscopy was used to find the percentage composition of the material, and structural and morphological studies of the samples were conducted using TEM and FESEM analyses. Photodegradation studies were performed for toluene removal, demonstrating a significant drop in toluene concentration in a short period (99.1% degradation in 150 min). A comparative investigation of the visible light photoactivity of WO3/Pt and TiO2 (P25) in water was conducted utilizing dye degradation tests, and WO3/Pt dominated with its excellent degradation efficiency.

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陶瓷过滤器支持的 WO3/Pt 光催化剂用于在可见光照射下净化室内空气†。
接触家庭空气污染会导致各种疾病,包括中风、缺血性心脏病、慢性阻塞性肺病(COPD)和肺癌。本研究开发了一种室内空气净化技术,该技术采用了由 WO3/Pt 涂层陶瓷泡沫过滤器(CFF)组成的可见光活化光催化剂。在可见光照射下,涂层多孔过滤器能够分解室内空气中普遍存在的污染物甲苯。具有开放孔隙的 CFF 相互连接的三维结构促进了光催化剂对甲苯的吸附和同步分解。XRD 分析表明,WO3/Pt 具有单斜晶体结构的氧化钨和不相溶的铂金属簇。比表面积和孔径采用 BET 法分析,能带隙采用 DRS 法测定。XRF 光谱法用于确定材料的百分比组成,而 TEM 和 FESEM 分析法则对样品的结构和形态进行了研究。对甲苯的去除进行了光降解研究,结果表明甲苯浓度在短时间内显著下降(150 分钟内降解 99.1%)。利用染料降解测试对 WO3/Pt 和 TiO2 (P25) 在水中的可见光光活性进行了比较研究,结果表明 WO3/Pt 以其出色的降解效率占据主导地位。
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