Snail mucus-inspired soybean meal adhesive with excellent mechanical strength and prepressing performance

IF 4.1 2区 化学 Q2 POLYMER SCIENCE Polymer Pub Date : 2024-11-26 DOI:10.1016/j.polymer.2024.127885
Fudong Zhang , Ying Zhu , Haoran Li , John Tosin Aladejana , Youming Dong , Kuang Li , Jiongjiong Li , Xiaona Li , Jianzhang Li
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Abstract

Plant-derived soybean protein adhesives have potential to replace petroleum-based resins. However, soybean protein adhesives generally face a compromise between bonding strength and toughness, and these adhesives display insufficient prepressing strength, hindering their further industrial application. Herein, inspired by the interface drainage snail mucus, we integrated electrostatic interaction and hydrogen bonding into adhesive network to achieve excellent mechanical strength and prepressing performance. Specifically, oppositely charged phytic acid functionalized boron nitride nanosheets (PA@BNNSs) and quaternized chitosan (QCS) formulated with soybean meal (SM) to produce the biomimetic adhesive. The electrostatic interaction formed between PA@BNNSs and QCS serves to enhance the cohesive strength of the adhesive in the wet state, while also improving its wettability. Benefiting from multiple interactions and nanomaterial reinforcement, the biomimetic adhesive achieved a prepressing strength of 0.65 MPa and wet shear strength of 2.53/1.50 MPa, which were 124 % and 80.7/117 % higher than the pure SM adhesive. In addition, the biomimetic adhesive exhibited good flame-retardant and mildew resistance properties. Therefore, this work offers a route to prepare advanced multifunctional bio-based adhesives.

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具有出色机械强度和预压性能的蜗牛粘液豆粕粘合剂
植物提取的大豆蛋白粘合剂有望取代石油基树脂。然而,大豆蛋白粘合剂通常面临着粘合强度和韧性之间的折衷,这些粘合剂显示出的预压强度不足,阻碍了其进一步的工业应用。在此,我们受蜗牛粘液界面排水的启发,将静电作用和氢键结合到粘合剂网络中,从而获得了优异的机械强度和预压性能。具体而言,将带相反电荷的植酸功能化氮化硼纳米片(PA@BNNSs)和季铵化壳聚糖(QCS)与豆粕(SM)配制成仿生粘合剂。PA@BNNSs 和 QCS 之间形成的静电相互作用可增强湿态粘合剂的内聚强度,同时还能改善其润湿性。得益于多重相互作用和纳米材料的增强,仿生粘合剂的预压强度达到 0.65 兆帕,湿剪切强度达到 2.53/1.50 兆帕,分别比纯 SM 粘合剂高出 124% 和 80.7/117%。此外,仿生物粘合剂还具有良好的阻燃性和防霉性。因此,这项工作为制备先进的多功能生物基粘合剂提供了一条途径。
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来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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