Self-powered photodetector with GeSe/WS2/MoS2 van der Waals heterojunctions

IF 4.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Sensors and Actuators A-physical Pub Date : 2024-11-26 DOI:10.1016/j.sna.2024.116080
ZHANG Yongzhi, HE Xunjun
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Abstract

Two-dimensional transition metal compounds and their heterojunction devices have been proven to have significant application value in the photodetector fields. With the deepening of energy-saving concepts, the self-powered photodetectors have undeniable advantages, including the requirement of no external power supply and strong environmental adaptability. However, most existing self-powered photodetectors suffer from the structure degradation, thereby resulting in slow response speed and low responsivity. Here, we report a self-powered GeSe/WS2/MoS2 photodetector with vertical van der Waals heterojunctions prepared by mechanical exfoliation. Such unique structure can not only effectively avoid the performance degradation or even failure caused by GeSe oxidation but also exhibit sensitive anisotropy and high rectification ratio. In the self-powered mode, the experimentally fabricated device shows the switching ratio of 3.2×103, the dark current of 1.1×10-13A, the responsivity of 14 mA/W, the external quantum efficiency of 4.1%, the detectivity of 7.3×108 Jones, and rise and fall time of 2.4 ms and 5.2 ms, respectively. In continuous high-frequency switching, moreover, the device can also operate stably. Therefore, such multi-heterojunctions provide new ideas for the designs of multifunctional self-powered photodetectors.

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采用 GeSe/WS2/MoS2 范德瓦尔斯异质结的自供电光电探测器
二维过渡金属化合物及其异质结器件已被证明在光电探测器领域具有重要的应用价值。随着节能理念的不断深入,自供电光电探测器具有无需外接电源、环境适应性强等不可否认的优势。然而,现有的自供电光电探测器大多存在结构退化问题,从而导致响应速度慢、响应率低。在此,我们报告了一种通过机械剥离法制备的具有垂直范德华异质结的自供电 GeSe/WS2/MoS2 光电探测器。这种独特的结构不仅能有效避免因 GeSe 氧化而导致的性能下降甚至失效,还能表现出灵敏的各向异性和高整流比。在自供电模式下,实验制备的器件开关比为 3.2×103,暗电流为 1.1×10-13A,响应度为 14 mA/W,外部量子效率为 4.1%,检测度为 7.3×108 Jones,上升和下降时间分别为 2.4 ms 和 5.2 ms。此外,在连续高频开关中,该器件也能稳定工作。因此,这种多异质结为设计多功能自供电光电探测器提供了新思路。
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来源期刊
Sensors and Actuators A-physical
Sensors and Actuators A-physical 工程技术-工程:电子与电气
CiteScore
8.10
自引率
6.50%
发文量
630
审稿时长
49 days
期刊介绍: Sensors and Actuators A: Physical brings together multidisciplinary interests in one journal entirely devoted to disseminating information on all aspects of research and development of solid-state devices for transducing physical signals. Sensors and Actuators A: Physical regularly publishes original papers, letters to the Editors and from time to time invited review articles within the following device areas: • Fundamentals and Physics, such as: classification of effects, physical effects, measurement theory, modelling of sensors, measurement standards, measurement errors, units and constants, time and frequency measurement. Modeling papers should bring new modeling techniques to the field and be supported by experimental results. • Materials and their Processing, such as: piezoelectric materials, polymers, metal oxides, III-V and II-VI semiconductors, thick and thin films, optical glass fibres, amorphous, polycrystalline and monocrystalline silicon. • Optoelectronic sensors, such as: photovoltaic diodes, photoconductors, photodiodes, phototransistors, positron-sensitive photodetectors, optoisolators, photodiode arrays, charge-coupled devices, light-emitting diodes, injection lasers and liquid-crystal displays. • Mechanical sensors, such as: metallic, thin-film and semiconductor strain gauges, diffused silicon pressure sensors, silicon accelerometers, solid-state displacement transducers, piezo junction devices, piezoelectric field-effect transducers (PiFETs), tunnel-diode strain sensors, surface acoustic wave devices, silicon micromechanical switches, solid-state flow meters and electronic flow controllers. Etc...
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