In this study, a surface plasmon resonance(SPR) sensor based on a phenanthroline self-assembled layer–modified silver-coated D-shaped plastic optical fiber (POF) was developed for the selective and real-time detection of Fe²⁺ ions in corrosive environments. The sensor structure was modeled and analyzed using COMSOL Multiphysics, with finite element simulations of the optical field to optimize the parameters of the fiber core, cladding, and metal film layers. The effective refractive index and near-field distribution of the plasmonic modes were systematically investigated.Simulation results indicated that when the silver film thickness was 40 nm and the phenanthroline molecular layer thickness was approximately 7 nm, the localized electric field confinement at the metal–dielectric interface was significantly enhanced, thereby improving resonance stability and sensitivity.Experimental results showed that the sensor exhibited a strong linear response toward Fe²⁺ within the concentration range of 120 pg·mL⁻¹ –1.2 μg·mL⁻¹ , with a resonance wavelength sensitivity of 3.832 nm·log(pg·mL⁻¹)⁻¹ and a corresponding refractive index sensitivity of 6669 nm·RIU⁻¹ . The limit of detection (LOD) reached 1.6 pg·mL⁻¹ , and the response time was approximately 10 s.The sensor showed excellent selectivity toward Fe²⁺ ions, with a pronounced spectral response compared to other commonly coexisting metal ions, such as Cu²⁺, Zn²⁺, Ni²⁺, Hg²⁺, Ca²⁺, and Mg²⁺.By combining multilayer structural synergy with chelation-based interfacial recognition, the proposed phenanthroline-modified D-shaped fiber SPR sensor exhibits high sensitivity, rapid response, and outstanding selectivity, highlighting its applicability for early-stage corrosion monitoring of underground and subsea metallic pipelines.
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