Modified fluorozirconate glasses doped with 4f- and 3d-cations

IF 3.8 3区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Optical Materials Pub Date : 2024-11-19 DOI:10.1016/j.optmat.2024.116456

Maria N. Brekhovskikh , Liudmila V. Moiseeva , Sergey Kh. Batygov , Valeria V. Vinokurova , Leonid A. Vaimugin , Natalia Y. Kirikova , Valentin A. Kondratyuk , Vladimir N. Makhov

{"title":"Modified fluorozirconate glasses doped with 4f- and 3d-cations","authors":"Maria N. Brekhovskikh , Liudmila V. Moiseeva , Sergey Kh. Batygov , Valeria V. Vinokurova , Leonid A. Vaimugin , Natalia Y. Kirikova , Valentin A. Kondratyuk , Vladimir N. Makhov","doi":"10.1016/j.optmat.2024.116456","DOIUrl":null,"url":null,"abstract":"<div><div>Fluoride glasses remain to be an attractive material for thirty years for optical applications lying in the visible and mid IR spectral range due to their low phonon energy (∼500-600 cm<sup>−1</sup>) and as a unique matrix for introducing rare earth activators. Modern materials science studies in the area of fluoride glasses are aimed at searching for the new modified compositions of these glasses with high optical homogeneity with the purpose of creating efficient active optical media in a wide spectral range. By modifying the composition of the glasses one can control the thermal, optical and spectroscopic properties for various applications. The information on glass-formation in the fluorozirconate system ZBLAN (ZrF<sub>4</sub>–BaF<sub>2</sub>–LaF<sub>3</sub>–AlF<sub>3</sub>–NaF) modified with “heavier” cations and anions, their physico-chemical and optical properties and areas of applications is presented in this review. Promising directions of practical application of such materials, doped with 4f- and 3d-cations in optoelectronics are discussed.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"158 ","pages":"Article 116456"},"PeriodicalIF":3.8000,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optical Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925346724016392","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Fluoride glasses remain to be an attractive material for thirty years for optical applications lying in the visible and mid IR spectral range due to their low phonon energy (∼500-600 cm⁻¹) and as a unique matrix for introducing rare earth activators. Modern materials science studies in the area of fluoride glasses are aimed at searching for the new modified compositions of these glasses with high optical homogeneity with the purpose of creating efficient active optical media in a wide spectral range. By modifying the composition of the glasses one can control the thermal, optical and spectroscopic properties for various applications. The information on glass-formation in the fluorozirconate system ZBLAN (ZrF₄–BaF₂–LaF₃–AlF₃–NaF) modified with “heavier” cations and anions, their physico-chemical and optical properties and areas of applications is presented in this review. Promising directions of practical application of such materials, doped with 4f- and 3d-cations in optoelectronics are discussed.

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

掺杂 4f- 和 3d 阳离子的改性氟锆酸玻璃

氟化物玻璃由于声子能量低（∼500-600 cm-1），并且是引入稀土活化剂的独特基质，三十年来一直是可见光和中红外光谱范围内光学应用的一种极具吸引力的材料。氟化玻璃领域的现代材料科学研究旨在寻找具有高光学均匀性的新型改性玻璃成分，目的是在宽光谱范围内创造高效的活性光学介质。通过改变玻璃的成分，人们可以控制玻璃的热学、光学和光谱特性，从而实现各种应用。本综述介绍了用 "重 "阳离子和阴离子修饰的氟锆酸盐体系 ZBLAN（ZrF4-BaF2-LaF3-AlF3-NaF）的玻璃形成、其物理化学和光学特性以及应用领域。还讨论了掺杂 4f- 和 3d 阳离子的此类材料在光电子学中的实际应用前景。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文去求助

来源期刊

Optical Materials 工程技术-材料科学：综合

CiteScore

6.60

自引率

12.80%

发文量

1265

审稿时长

38 days

期刊介绍： Optical Materials has an open access mirror journal Optical Materials: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. The purpose of Optical Materials is to provide a means of communication and technology transfer between researchers who are interested in materials for potential device applications. The journal publishes original papers and review articles on the design, synthesis, characterisation and applications of optical materials. OPTICAL MATERIALS focuses on: • Optical Properties of Material Systems; • The Materials Aspects of Optical Phenomena; • The Materials Aspects of Devices and Applications. Authors can submit separate research elements describing their data to Data in Brief and methods to Methods X.