Melt Spinnability Comparison of Mechanically and Chemically Recycled Polyamide 6 for Plastic Waste Reuse.

IF 4.7 3区 工程技术 Q1 POLYMER SCIENCE Polymers Pub Date : 2024-11-12 DOI:10.3390/polym16223152
Kyuhyun Kim, Minsoo Kim, Yerim Kim, Jinhyeong Kim, Jihwan Lim, Woojin Lee, Han Seong Kim, Dong-Hyun Cho, Jaejun Lee, Sejin Choi
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Abstract

With the increasing volume of synthetic fiber waste, interest in plastic reuse technologies has grown. To address this issue, physical and chemical recycling techniques for polyamide, a major component of textile waste, have been developed. This study investigates the remelting and reforming properties of four types of pristine and recycled polyamide 6, focusing on how the microstructural arrangement of recycled polyamides affects polymer fiber formation. DSC and FT-IR were used to determine the thermal properties and chemical composition of the reformed thin films. Differences in the elongation behavior of molten fibers during the spinning process were also observed, and the morphology of the resulting fibers was examined via SEM. Birefringence analysis revealed that the uniformity of the molecular structure greatly influenced differences in the re-fiberization process, suggesting that chemically recycled polyamide is the most suitable material for re-fiberization with its high structural similarity to pristine polyamide.

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用于塑料废物再利用的机械回收聚酰胺 6 与化学回收聚酰胺 6 的熔融纺丝性比较。
随着合成纤维废料数量的不断增加,人们对塑料再利用技术的兴趣也与日俱增。为了解决这个问题,人们开发了聚酰胺(纺织废料的主要成分)的物理和化学回收技术。本研究调查了四种原始聚酰胺 6 和回收聚酰胺 6 的重熔和重整特性,重点关注回收聚酰胺的微结构排列如何影响聚合物纤维的形成。使用 DSC 和 FT-IR 测定重整薄膜的热性能和化学成分。此外,还观察了熔融纤维在纺丝过程中的伸长行为差异,并通过扫描电子显微镜(SEM)检查了所生成纤维的形态。双折射分析表明,分子结构的均匀性在很大程度上影响着再纤维化过程中的差异,这表明化学回收聚酰胺是最适合再纤维化的材料,因为其结构与原始聚酰胺高度相似。
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来源期刊
Polymers
Polymers POLYMER SCIENCE-
CiteScore
8.00
自引率
16.00%
发文量
4697
审稿时长
1.3 months
期刊介绍: Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.
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