Citrus fibers improve rheology of OSA starch-based high internal phase emulsion for 3D printed elderly foods.

Fan Yang, Dong Jiang, Qiuhui Hu
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Abstract

3D printing ready-to-eat emulsions using trans-fat-free edible oil, presents a significant challenge due to the complexities involved in achieving the necessary material structure, rheological properties, and stability. This study fabricated High Internal Phase Emulsions (HIPEs) stabilized with citrus fibers and octenyl succinic anhydride (OSA) modified waxy starch, serving as the printable inks for 3D-printable elderly foods. These printable inks exhibited a pseudoplastic gel structure, which provided enhanced extrudability and improved shape retention. The incorporation of citrus fiber, water, OSA starch, sunflower oil at a concentration of 0.3 wt%, 22.7 % wt %, 2 % wt%, 75 wt% in the 3D-printed HIPEs resulted in optimal addition, yielding the highest level of shape accuracy. Compared to the addition of OSA-modified starch, microstructural analysis and rheological testing (using Lissajous-Bowditch plots) indicated that the addition of citrus fiber had a greater impact on the rheological and textural properties of the HIPEs, which improved shape retention and fluidity of the HIPEs, and ensure the stability of continuous extrusion printing. Additionally, bionic tribological properties demonstrated that tribological properties of the prepared HIPEs were very close to the ones of mayonnaise, which indicating that the prepared HIPEs had smooth texture and easy-to-chew properties for the elderly. These findings offered a comprehensive understanding of the structure-function relationship between the molecular structures of HIPEs and their 3D printability, providing technical insights for the development of 3D-printed emulsion-based ready-to-eat elderly food products. This study provided a good industrialized method for HIPEs stabilized with only fruit dietary fiber and modified starch, and facilitated the development of emulsion-based ready-to-eat food products with 3D printability.

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柑橘纤维改善了基于 OSA 淀粉的高内相乳液的流变性,适用于 3D 打印老年食品。
使用不含反式脂肪的食用油进行三维打印即食乳剂是一项重大挑战,因为要实现必要的材料结构、流变特性和稳定性非常复杂。本研究利用柑橘纤维和辛烯基琥珀酸酐(OSA)改性蜡质淀粉稳定高内相乳液(HIPE),并将其作为可打印油墨,用于 3D打印老年食品。这些可打印油墨呈现出一种假塑性凝胶结构,可提高挤出性和形状保持性。将柑橘纤维、水、OSA淀粉、葵花籽油分别以0.3 wt%、22.7 % wt%、2 % wt%、75 wt%的浓度加入3D打印的HIPE中,可获得最佳添加效果,使形状精度达到最高水平。与添加 OSA 改性淀粉相比,微观结构分析和流变测试(使用 Lissajous-Bowditch 图)表明,添加柑橘纤维对 HIPE 的流变和纹理特性影响更大,从而改善了 HIPE 的形状保持性和流动性,并确保了连续挤出打印的稳定性。此外,仿生摩擦学特性表明,制备的 HIPE 的摩擦学特性与蛋黄酱非常接近,这表明制备的 HIPE 具有光滑的质地和易于老年人咀嚼的特性。这些研究结果为全面了解HIPE分子结构与3D打印性能之间的结构-功能关系提供了依据,为开发基于3D打印乳液的老年人即食食品提供了技术启示。该研究为仅使用水果膳食纤维和变性淀粉稳定HIPEs提供了一种良好的工业化方法,促进了具有3D打印性的乳液型即食食品的开发。
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