Thermal behavior of metallic fuel pyrotechnics of Al, Mg and alloy of Al–Mg: a review

IF 3 3区工程技术 Q2 CHEMISTRY, ANALYTICAL Journal of Thermal Analysis and Calorimetry Pub Date : 2024-11-14 DOI:10.1007/s10973-024-13800-6

Hamid Reza Pouretedal, Mohammad Hosein Roudashti

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Abstract

Pyrotechnics are among the energetic materials that have wide applications in various military and civilian fields. Thermal behavior and thermal stability are the very important properties of pyrotechnics. The thermal stability of a pyrotechnic shows the scope of application as well as safety. Thermal analysis methods such as TGA, DTA, and DSC are used to obtain information on the thermal behavior and thermal stability of pyrotechnics. The first review in the field of thermal analysis of pyrotechnics was published by P.G. LAYE and E.L. CHARSLEY in Thermochimica Acta Journal in 1987. The results of thermal analysis of pyrotechnics containing molybdenum trioxide, lead oxides, nitrates, perchlorates and chlorates, dichromates and chromates have been reviewed and discussed in mentioned paper. Over time, investigating the thermal behavior of pyrotechnics can be useful for scientists in this scientific field. It is possible to consider various divisions for pyrotechnics based on the type of fuel, type of oxidizer, etc. In the present paper, the results of the thermal behavior of pyrotechnics are reviewed and discussed based on the type of metallic fuel including the common metals aluminum, magnesium, and Al–Mg alloy (magnalium).

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铝、镁和铝镁合金金属燃料烟火的热行为：综述

烟火剂属于高能材料，在各种军事和民用领域都有广泛的应用。热行为和热稳定性是烟火剂非常重要的特性。烟火剂的热稳定性显示了其应用范围和安全性。TGA、DTA 和 DSC 等热分析方法可用于获取有关烟火剂热行为和热稳定性的信息。1987 年，P.G. LAYE 和 E.L. CHARSLEY 在 Thermochimica Acta 期刊上发表了第一篇烟火剂热分析领域的综述。文中对含有三氧化钼、氧化铅、硝酸盐、高氯酸盐和氯酸盐、重铬酸盐和铬酸盐的烟火剂的热分析结果进行了回顾和讨论。随着时间的推移，研究烟火剂的热行为对这一科学领域的科学家很有帮助。可以根据燃料类型、氧化剂类型等对烟火进行不同的划分。本文根据金属燃料的类型，包括常见的金属铝、镁和铝镁合金（镁），对烟火剂的热行为结果进行了回顾和讨论。

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来源期刊

Journal of Thermal Analysis and Calorimetry 化学-分析化学

CiteScore

8.50

自引率

9.10%

发文量

577

审稿时长

3.8 months

期刊介绍： Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews. The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.