High entropy engineering boosts thermo-mechanical properties of rare-earth tantalates: Influences of cocktail effects

Abstract

High entropy engineering has been widely used to optimize properties of various materials, and we improve comprehensive performance of rare-earth tantalates RETaO₄ (RE is rare earth) by changing configurational entropy in this work. Four medium/high entropy RETaO₄ (M/HERT) are successfully prepared, and the variations of disorders and distortion degree of lattices with the increasing configurational entropy are described in detail. It is revealed that M/HERT with the highest configurational entropy does not correspond to the best comprehensive properties. Unexpected variations in properties of M/HERT compared to RETaO₄ are observed. By comparing with values obtained from rule of mixture (ROM), it is believed that the cocktail effect exists in M/HERT. The synergistic optimizations of thermo-mechanical properties are realized, including reducing thermal conductivity, increasing thermal expansion coefficients (TECs), and enhancing mechanical properties. M/HERT exhibit excellent high temperature stability and provide a good thermal insulation gradient, which is significant for high-temperature applications of RETaO₄. This work serves as an important part for thermal barrier coatings materials with high working temperatures and low thermal conductivity.