Oleg V. Khazipov, Anastasia S. Pyatachenko, Victor M. Chernyshev
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引用次数: 0
Abstract
A user-friendly and highly efficient mechanochemical synthesis of Ni/NHC complexes of the general formula (NHC)Ni(Cp)Cl (NHC is an N-heterocyclic carbene ligand; Cp is the cyclopentadienyl anion) under aerobic conditions is reported. The reaction between nickelocene and azolium salts (NHC proligands) proceeds with good to excellent yields of (NHC)Ni(Cp)Cl in the presence of a K2CO3 additive, which reduces the clumping of the reaction mixture. The developed process can be scaled up on a planetary ball mill.
期刊介绍：
Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications.
Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.
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