Dmitriy A. Bokarev, Galina O. Bragina, Artem R. Kolyadenkov, Alexander V. Kazakov, Alexander Yu. Stakheev
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引用次数: 0
Abstract
The performance of Mn/Beta in ozone catalytic oxidation (OZCO) of n-butane was optimized by variation of the Mn content (0.6–10 wt%) and localization of Mn species in the zeolite structure (as Mn2+ ions in the cationic position or MnOx species). It was found that localization of Mn2+ ions in the cationic positions of the zeolite favors high efficiency of ozone utilization in the OZCO process by minimizing O3 consumption, while the formation of Mn oxide species improves the catalyst activity at a low temperature (50–70 °C), though at the expense of the ozone utilization efficiency.
期刊介绍:
Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications.
Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.