Microstructure and kinetic evolutions of multi-variants lamella in γ-TiAl alloys

IF 7.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials & Design Pub Date : 2024-12-01 DOI:10.1016/j.matdes.2024.113478
Zan Zhang , Jicheng Zhuo , Kunning Niu , Peng Sang , Shenglong Wang , Haiwei Zhang , Yongsheng Li
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Abstract

The D019-α2 / L10-γ alternate lamellae microstructure in TiAl alloys brings the superior mechanical property, the lamellae with multi-variant γ phase are key characteristic of morphology-property causality. The nucleation, growth and coarsening of multi-variants γ are investigated in TiAl alloys by using the three-dimensional phase-field simulation, the γ morphology, lamellar spacing (LS) and the predicted yield strength of alloy are in agreement with the experiment. It is found that the γ variants can nucleate and grow up separately to form the single-variant lamella, or through the symbiotic nucleation and growth to form multi-variant lamella, the growth of γ lamella follows the terrace-ledge-kink mechanism. The growth rate along the longitudinal direction is distinctly larger than that of the thickness direction, resulting in the lamellar structure. A three-stage growth kinetics, nucleation, growth and coarsening of γ lamella in thickness is revealed. As Al content changes, the LS is enlarged with the reduced lamella number. The influence of the LS on the mechanical properties is evaluated by using the Hall-Petch relationship. The results give an insight for the formation and evolution mechanisms of multi-variant γ lamella, and discover the internal relations of lamellar morphology and mechanical properties of TiAl alloys.

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γ-TiAl合金中多变体薄片的显微组织与动力学演变
TiAl合金中的D019-α2 / L10-γ互变片层组织带来了优异的力学性能,多相γ片层是TiAl合金形貌-性能因果关系的关键特征。采用三维相场模拟方法研究了TiAl合金中多种变体γ的形核、生长和粗化过程,合金的γ形貌、片层间距(LS)和屈服强度与实验结果一致。发现γ变异体可以单独成核长大形成单变异体片层,也可以通过共生成核长大形成多变异体片层,γ变异体片层的生长遵循梯田-边缘-扭结机制。沿纵向的生长速率明显大于沿厚度方向的生长速率,形成片层结构。揭示了γ薄片在厚度上的成核、生长和粗化三个阶段的生长动力学。随着Al含量的变化,LS随片层数的减少而增大。利用Hall-Petch关系评价了LS对材料力学性能的影响。研究结果揭示了多相γ片层的形成和演化机制,揭示了TiAl合金片层形貌与力学性能之间的内在联系。
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来源期刊
Materials & Design
Materials & Design Engineering-Mechanical Engineering
CiteScore
14.30
自引率
7.10%
发文量
1028
审稿时长
85 days
期刊介绍: Materials and Design is a multi-disciplinary journal that publishes original research reports, review articles, and express communications. The journal focuses on studying the structure and properties of inorganic and organic materials, advancements in synthesis, processing, characterization, and testing, the design of materials and engineering systems, and their applications in technology. It aims to bring together various aspects of materials science, engineering, physics, and chemistry. The journal explores themes ranging from materials to design and aims to reveal the connections between natural and artificial materials, as well as experiment and modeling. Manuscripts submitted to Materials and Design should contain elements of discovery and surprise, as they often contribute new insights into the architecture and function of matter.
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