Modulating Ion Deposition and Crystallization of Sputtered Perovskite Films for Efficient and Stable Solar Cells

IF 8.7 1区 化学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY ACS Materials Letters Pub Date : 2024-11-04 DOI:10.1021/acsmaterialslett.4c01743
Bo Gao, Zhuang Zuo, Jing Hu, Qi Qi, Zongyang Peng, Shaocong Hou, Yongping Fu* and Dechun Zou*, 
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Abstract

Perovskite films with excellent photoelectric properties play a significant role in fabricating high-performance solar cells. Magnetron sputtering is a commercially available and highly reliable technique that is highly attractive for applications in the production of perovskite films. Here, the ion deposition of the step-by-step sputtering process and the continuous sputtering process was systematically explored to realize the controlled ion deposition and crystallization of sputtered perovskite films. We found that the deposition rate of organic components in the initial sputtering stage is greater than that of inorganic components, leading to the ion ratio of perovskite thin films being accurately regulated by adjusting the sputtering time. Furthermore, the injected content of methylammonium bromide will significantly affect the ion ratios and crystal structures of the sputtered perovskite films. The efficiency and stability of sputtered perovskite solar cells can be enhanced significantly by optimizing the sputtered processes and improving the crystallization, which lay a solid foundation for further study of the preparation of perovskite solar cells by magnetron sputtering.

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高效稳定太阳能电池用溅射钙钛矿薄膜的调制离子沉积和结晶
钙钛矿薄膜具有优良的光电性能,在高性能太阳能电池的制造中发挥着重要作用。磁控溅射是一种商业上可用的、高度可靠的技术,在钙钛矿薄膜的生产中具有很高的应用吸引力。本文系统探索了分步溅射和连续溅射过程中的离子沉积,实现了可控的离子沉积和溅射钙钛矿薄膜的结晶。我们发现,在初始溅射阶段,有机组分的沉积速率大于无机组分的沉积速率,从而可以通过调整溅射时间来精确调节钙钛矿薄膜的离子比。此外,甲基溴化铵的注入量会显著影响溅射钙钛矿薄膜的离子比和晶体结构。通过优化溅射工艺和改进晶化工艺,可以显著提高溅射钙钛矿太阳能电池的效率和稳定性,为进一步研究磁控溅射制备钙钛矿太阳能电池奠定坚实的基础。
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来源期刊
ACS Materials Letters
ACS Materials Letters MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
14.60
自引率
3.50%
发文量
261
期刊介绍: ACS Materials Letters is a journal that publishes high-quality and urgent papers at the forefront of fundamental and applied research in the field of materials science. It aims to bridge the gap between materials and other disciplines such as chemistry, engineering, and biology. The journal encourages multidisciplinary and innovative research that addresses global challenges. Papers submitted to ACS Materials Letters should clearly demonstrate the need for rapid disclosure of key results. The journal is interested in various areas including the design, synthesis, characterization, and evaluation of emerging materials, understanding the relationships between structure, property, and performance, as well as developing materials for applications in energy, environment, biomedical, electronics, and catalysis. The journal has a 2-year impact factor of 11.4 and is dedicated to publishing transformative materials research with fast processing times. The editors and staff of ACS Materials Letters actively participate in major scientific conferences and engage closely with readers and authors. The journal also maintains an active presence on social media to provide authors with greater visibility.
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