Enrichment and sources of major and trace elements in the Qinghai-Tibetan Plateau: a case study of the Golog Prefecture

Abstract

The Qinghai-Tibet Plateau (QTP) is a vital region for global atmospheric circulation and biodiversity. This study aims to evaluate the contents and enrichment status of 25 soil elements, namely Al, As, Ca, Cd, Co, Cr, Cu, K, Mg, Mn, Mo, N, Na, Ni, P, Pb, S, Sc, Si, Sn, Sr, Fe, Ti, V, and Zn, in the plateau region. Specifically, our analysis revealed that As exhibited significant enrichment near fault zones and intrusive rocks, while Ca was mainly enriched due to the dissolution of carbonate rocks. Additionally, Principal Component Analysis and Multiple Linear Regression (PCA-MLR) were used to examine the origins of these elements. The potential ecological risk posed by Cd and Pb was evaluated and found to be negligible. Soil element enrichment in the QTP was mainly influenced by lithology, and high spatial variability was observed in As, Ca, and S, which were mainly affected by geological processes and grazing activities. Six sources of elements in the plateau region were identified, namely geological mixed sources, grazing activities, alkaline granite, ultrabasic rocks, fault zones and intrusive rocks, as well as atmospheric deposition. Among these, geological mixed sources and grazing activities were determined to be the priority contributors. Although grazing activities on the QTP as well as atmospheric deposition at long distances caused the enrichment of elements in the area, the ecological risk was negligible. The outcomes of this work can be used as a theoretical basis for prospective investigation on the stability of high-altitude ecosystems, species diversity, and geochemical background.