Flat dispersion at large momentum transfer at the onset of exciton polariton formation

Abstract

Excitons are quasiparticles, comprised of an electron excited from the valence band and attracted to the hole left behind, that govern transport properties in transition metal dichalcogenides. Excitonic coherence specifically needs to be understood to realise applications based on Bose-Einstein condensation and superfluidity. Here we used momentum-resolved electron energy-loss spectroscopy to obtain the complete energy-momentum dispersion of excitons in thin film and monolayer WSe2 across the entire Brillouin zone, including outside of the light cone and for a large energy-loss range (1.5–4 eV). The measured dispersion of the modes was found to be flat. This suggests that the excitations are at the onset of polaritonic mode formation, propagating in the confinement of nanometer thin and monolayer WSe2. In combination with helium ion microscopy nanopatterning it was possible to probe and control these excitonic modes in thin film WSe2 by modifying the local geometry through nanosized cuts. The coupling of an exciton to an electromagnetic field leads to the formation of an exciton polariton and in transition metal dichalcogenides specifically, they might be candidates for room temperature Bose-Einstein condensation. Here, the authors observe excitons at the onset of polaritonic mode formation in the confinement of nanometer thin and monolayer WSe2. Excitonic intensities were controlled locally by nanosized modifications to the material’s geometry.