eCoral: How Electrolysis Could Restore Seawater Conditions Ideal for Coral Reefs

IF 4.6 2区 化学 Q2 CHEMISTRY, PHYSICAL The Journal of Physical Chemistry Letters Pub Date : 2024-12-03 DOI:10.1021/acs.jpclett.4c02715
Eric W. Lees, Christophe Tournassat, Adam Z. Weber, Pupa U. P. A. Gilbert
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Abstract

Coral reefs suffer from climate change, including long-term ocean acidification (OA) and warming and short-term bleaching, tropical storms, and pollution events, all of which are increasing in frequency and severity. It is urgent yet unclear how to intervene to save coral reefs. Reversal of the ocean pH to preindustrial levels could restore coral reefs to their preindustrial growth rates; however, strategies to reverse OA on environmentally relevant scales have not been established. Anecdotally, electrolysis seems to help coral reefs recover from acidification and short-term events, but few uncontrolled studies support such claims. Here, using two independent continuum simulation approaches (COMSOL and CrunchFlow), we show the effect of electrolysis on seawater chemistry relevant to coral reef survival and growth. We conclude that near the negative electrodes, the cathodes, seawater pH, supersaturation, and carbonate concentration all increase significantly. Electrolysis of seawater, therefore, can be used to restore preindustrial ocean conditions locally to save coral reefs, an approach termed eCoral here. We anticipate these simulation results to be the starting point for controlled experiments to test whether seawater electrolysis promotes coral reef growth and restoration, as these simulations predict.

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生态:电解如何恢复珊瑚礁理想的海水条件
珊瑚礁受到气候变化的影响,包括长期的海洋酸化(OA)和变暖,以及短期的漂白,热带风暴和污染事件,所有这些事件的频率和严重程度都在增加。如何干预以拯救珊瑚礁迫在眉睫,但尚不清楚。将海洋pH值恢复到工业化前的水平可以使珊瑚礁恢复到工业化前的生长速度;然而,在与环境有关的尺度上扭转OA的战略尚未确立。有趣的是,电解似乎有助于珊瑚礁从酸化和短期事件中恢复过来,但很少有未经控制的研究支持这种说法。在这里,我们使用两种独立的连续体模拟方法(COMSOL和CrunchFlow),展示了电解对与珊瑚礁生存和生长相关的海水化学的影响。在负极附近,阴极、海水pH、过饱和度和碳酸盐浓度均显著增加。因此,电解海水可以用来恢复当地工业化前的海洋环境,以拯救珊瑚礁,这种方法在这里被称为eCoral。我们预计这些模拟结果将成为对照实验的起点,以测试海水电解是否如这些模拟预测的那样促进珊瑚礁的生长和恢复。
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来源期刊
The Journal of Physical Chemistry Letters
The Journal of Physical Chemistry Letters CHEMISTRY, PHYSICAL-NANOSCIENCE & NANOTECHNOLOGY
CiteScore
9.60
自引率
7.00%
发文量
1519
审稿时长
1.6 months
期刊介绍: The Journal of Physical Chemistry (JPC) Letters is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, chemical physicists, physicists, material scientists, and engineers. An important criterion for acceptance is that the paper reports a significant scientific advance and/or physical insight such that rapid publication is essential. Two issues of JPC Letters are published each month.
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