Crystalline potassium boryl dithiolate and diselenolate†

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-11-25 DOI:10.1039/D4CC05240D
Yuyang Dai, Yu Wang, Liliang Wang, Fan Qi, Qianli Li and Lingbing Kong
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Abstract

Both the B–S and S–S bonds of 1,2,4,3,5-trithiadiborolane 1 could be cleaved by potassium graphite (KC8) to give the first isolable boryl dithiolate DmpB(SK)23, whereas the reduction of 1,2,4-triselena-3,5-diborolane 2 with KC8 afforded the boryl diselenolate DmpB(SeK)(SeSeK) 4, showcasing the unprecedented structural authentication of ligand substituted diselenolate.

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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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