{"title":"The use of NiI2 as a catalyst for CO2 addition to oxiranes: activation methods","authors":"S. E. Lyubimov, P. V. Cherkasova","doi":"10.1007/s11172-024-4426-0","DOIUrl":null,"url":null,"abstract":"<div><p>Nickel(<span>ii</span>) iodide with organic and inorganic additives was tested in the addition of CO<sub>2</sub> to oxiranes. The introduction of diethylamine leads to the formation of an effective catalyst, which is, in some cases, capable of completing the reaction in the presence of 1 mol.% NiI<sub>2</sub> over a period of 1 h.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"73 10","pages":"3090 - 3093"},"PeriodicalIF":1.7000,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-024-4426-0","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Nickel(ii) iodide with organic and inorganic additives was tested in the addition of CO2 to oxiranes. The introduction of diethylamine leads to the formation of an effective catalyst, which is, in some cases, capable of completing the reaction in the presence of 1 mol.% NiI2 over a period of 1 h.
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
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