S. V. Safronov, S. A. Kuklin, N. V. Abramova, Yu. V. Nelyubina
{"title":"New ferrocene- and ruthenocene-based nickel pincer complexes","authors":"S. V. Safronov, S. A. Kuklin, N. V. Abramova, Yu. V. Nelyubina","doi":"10.1007/s11172-024-4399-z","DOIUrl":null,"url":null,"abstract":"<div><p>First ferrocene- and ruthenocene-based nickel pincer complexes, NiCl[{2,5-(Bu<sup>t</sup><sub>2</sub>PCH<sub>2</sub>)<sub>2</sub>C<sub>5</sub>H<sub>2</sub>}Fe(C<sub>5</sub>H<sub>5</sub>)] (<b>3a</b>) and NiCl[{2,5-(Bu<sup>t</sup><sub>2</sub>PCH<sub>2</sub>)<sub>2</sub>C<sub>5</sub>H<sub>2</sub>}Ru(C<sub>5</sub>H<sub>5</sub>)] (<b>3b</b>), respectively, were synthesized and characterized by <sup>1</sup>H, <sup>31</sup>P{<sup>1</sup>H}, and <sup>13</sup>C{<sup>1</sup>H} NMR spectroscopy. The structure of complex 3<b>b</b> was established by single-crystal X-ray diffraction.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"73 10","pages":"2831 - 2837"},"PeriodicalIF":1.7000,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-024-4399-z","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
First ferrocene- and ruthenocene-based nickel pincer complexes, NiCl[{2,5-(But2PCH2)2C5H2}Fe(C5H5)] (3a) and NiCl[{2,5-(But2PCH2)2C5H2}Ru(C5H5)] (3b), respectively, were synthesized and characterized by 1H, 31P{1H}, and 13C{1H} NMR spectroscopy. The structure of complex 3b was established by single-crystal X-ray diffraction.
期刊介绍:
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.