Developing chiral aggregates exhibiting anti-S-shaped CD-ee dependence: using a meso-isomer to tune dynamic aggregates induced by enantiomers†

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-12-20 DOI:10.1039/d4cc05345a
Xiao-Yan Lin , Jin-Ling Shi , Qian Wang , Yue-Bo Yu , Xuan-Xuan Chen , Xiaosheng Yan , Xin Wu , Jian-Bin Lin , Zhao Li , Yun-Bao Jiang
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Abstract

We report the use of the meso-isomer of tartaric acid, meso-tartaric acid, to tune the chirality of the dynamic aggregates of a perylenebisimide dye bearing boronic acid groups in the presence of enantiomeric l-/d-tartaric acid. The CD-ee dependence changes from S- to anti-S-shaped. A change in the structures of the chiral aggregates led by the meso-tartaric acid is identified.

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开发具有抗s形CD-ee依赖性的手性聚集体:使用中位异构体调节由对映体诱导的动态聚集体
我们报道了使用酒石酸的中位异构体,中位酒石酸,在L-/ d -酒石酸对映体存在的情况下,调整含硼酸基团的苝酰二亚胺染料的动态聚集体的手性。CD-ee的依赖关系由S型变为反S型。发现了中位酒石酸引起的手性聚集体结构的变化。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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