{"title":"Developing chiral aggregates exhibiting anti-S-shaped CD-ee dependence: Using meso-isomer to tune dynamic aggregates induced by enantiomers","authors":"Xiao-Yan Lin, Jin-Ling Shi, Qian Wang, Yue-Bo Yu, Xuan-Xuan Chen, Xin Wu, Xiaosheng Yan, Jianbin Lin, Zhao Li, Yun-Bao Jiang","doi":"10.1039/d4cc05345a","DOIUrl":null,"url":null,"abstract":"We report the use of the meso-isomer of tartaric acid, meso-tartaric acid, to tune the chirality of the dynamic aggregates of a perylenebisimide dye bearing boronic acid groups in the presence of enantiomeric L-/D-tartaric acid. The CD-ee dependence changes from S- to anti-S-shaped. A change in the structures of the chiral aggregates led by the meso-tartaric acid is identified.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"47 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4cc05345a","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
We report the use of the meso-isomer of tartaric acid, meso-tartaric acid, to tune the chirality of the dynamic aggregates of a perylenebisimide dye bearing boronic acid groups in the presence of enantiomeric L-/D-tartaric acid. The CD-ee dependence changes from S- to anti-S-shaped. A change in the structures of the chiral aggregates led by the meso-tartaric acid is identified.
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