Design of a Renewable Methanol Production Process from Biogas: Analysis of the Influence of the Operating Pressure in the Synthesis Loop

IF 3.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Industrial & Engineering Chemistry Research Pub Date : 2024-12-10 DOI:10.1021/acs.iecr.4c03170
M. Victoria Del Pópolo Grzona, Eduardo M. Izurieta, Eduardo López, Marisa N. Pedernera
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Abstract

This study presents the design and analysis of an energy-integrated process for producing green methanol from biogas. Emphasizing the need for sustainable fuel solutions, the paper explores the use of biogas, purified to biomethane, as a feedstock for methanol synthesis. The process involves a convective reformer with bayonet-type tubes for syngas production and a multitubular methanol synthesis reactor. The integration of thermal energy is a core feature, ensuring the process is self-sufficient. Key aspects analyzed include the impact of methanol synthesis loop pressure (30–90 bar) on performance metrics such as carbon and energy efficiency and CAPEX/OPEX of the loop. An optimum operating pressure of 40 bar was found. Simulation results indicate high methane conversion in the reformer (87.34%) and effective internal heat recovery due to the bayonet-type tubes (19%). The overall process achieves a carbon efficiency of 48.5% and an energy efficiency of around 64%.

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沼气再生甲醇生产工艺设计:合成回路操作压力影响分析
本研究介绍了从沼气中生产绿色甲醇的能源集成工艺的设计和分析。强调需要可持续的燃料解决方案,论文探讨了沼气的使用,纯化为生物甲烷,作为甲醇合成的原料。该工艺包括一个带有用于合成气生产的卡口式管的对流重整器和一个多管甲醇合成反应器。热能的集成是一个核心特征,确保了工艺的自给自足。分析的关键方面包括甲醇合成回路压力(30-90 bar)对性能指标的影响,如碳和能源效率以及循环的CAPEX/OPEX。最佳操作压力为40bar。模拟结果表明,该装置的甲烷转化率较高(87.34%),且由于卡口式管的存在,其内部热回收效果较好(19%)。整个过程的碳效率为48.5%,能源效率约为64%。
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来源期刊
Industrial & Engineering Chemistry Research
Industrial & Engineering Chemistry Research 工程技术-工程:化工
CiteScore
7.40
自引率
7.10%
发文量
1467
审稿时长
2.8 months
期刊介绍: ndustrial & Engineering Chemistry, with variations in title and format, has been published since 1909 by the American Chemical Society. Industrial & Engineering Chemistry Research is a weekly publication that reports industrial and academic research in the broad fields of applied chemistry and chemical engineering with special focus on fundamentals, processes, and products.
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