{"title":"Reshaping quinolines by single-electron-transfer-triggered dearomatization","authors":"Yun-Peng Chu , Jiajia Ma","doi":"10.1016/j.chempr.2024.11.007","DOIUrl":null,"url":null,"abstract":"<div><div>In this issue of <em>Chem</em>, Prof. Shunsuke Chiba, Prof. Derek Pratt, and their colleagues report a groundbreaking study on the dearomative dimerization and skeletal rearrangement of quinolines under polysulfide anion photocatalysis. This work demonstrates a unique method for transforming quinolines into complex sp<sup>3</sup>-rich polyheterocycles and 4-(3-indolylmethyl)quinolines through a sequence of reactions initiated by single-electron transfer (SET).</div></div>","PeriodicalId":268,"journal":{"name":"Chem","volume":"10 12","pages":"Pages 3529-3531"},"PeriodicalIF":19.1000,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chem","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2451929424005916","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
In this issue of Chem, Prof. Shunsuke Chiba, Prof. Derek Pratt, and their colleagues report a groundbreaking study on the dearomative dimerization and skeletal rearrangement of quinolines under polysulfide anion photocatalysis. This work demonstrates a unique method for transforming quinolines into complex sp3-rich polyheterocycles and 4-(3-indolylmethyl)quinolines through a sequence of reactions initiated by single-electron transfer (SET).
期刊介绍：
Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.
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