{"title":"Transformative ligand effects in iron photocatalysis","authors":"Luisa Zach , Jola Pospech","doi":"10.1016/j.chempr.2024.11.008","DOIUrl":null,"url":null,"abstract":"<div><div>Iron photocatalysis has been constrained by a lack of tunable ligands for diverse substrate scopes. Ackerman-Biegasiewicz et al. demonstrate diethylenetriamine (DETA) as a transformative ligand in Fe-catalyzed Giese-type additions recently in <em>Chem Catalysis</em>. This platform enables effective coupling of substrates with free amines, alcohols, and boronic esters, highlighting iron’s potential as a sustainable alternative to precious metals in photoredox catalysis.</div></div>","PeriodicalId":268,"journal":{"name":"Chem","volume":"10 12","pages":"Pages 3531-3533"},"PeriodicalIF":19.6000,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chem","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2451929424005928","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Iron photocatalysis has been constrained by a lack of tunable ligands for diverse substrate scopes. Ackerman-Biegasiewicz et al. demonstrate diethylenetriamine (DETA) as a transformative ligand in Fe-catalyzed Giese-type additions recently in Chem Catalysis. This platform enables effective coupling of substrates with free amines, alcohols, and boronic esters, highlighting iron’s potential as a sustainable alternative to precious metals in photoredox catalysis.
期刊介绍：
Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.
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