Guilherme Cariello , Rafael D. C. Gallo , Victor M. Deflon , Rodrigo A. Cormanich , Igor D. Jurberg
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引用次数: 0
Abstract
A reaction sequence of visible light-mediated cyclopropanation/acid-promoted ring-opening is described for the formal alkylation of silyl enol ethers with aryldiazoacetates. Under the same conditions, the Danishefsky's diene can react with aryldiazoacetates to afford [4+1]-cycloaddition adducts. Key mechanistic aspects are proposed based on experimental evidence and DFT calculations.
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