{"title":"Charge-dependent hierarchical self-assembling of fluorinated gold nanoclusters†","authors":"Yuki Saito , Duhong Sun , Hayato Kanai , Yasuhiro Ishida , Hideyuki Mitomo , Kuniharu Ijiro , Katsuaki Konishi","doi":"10.1039/d4cc04786a","DOIUrl":null,"url":null,"abstract":"<div><div>Au<sub>25</sub>(SR)<sub>18</sub> nanoclusters decorated with semifluorinated thiolate ligands (SFLs) self-assemble hierarchically depending on the charge state of the nanocluster component; the use of the anionic cluster ([Au<sub>25</sub>]<sup>−</sup>) resulted in the generation of nanofibers, whereas the neutral counterpart ([Au<sub>25</sub>]<sup>0</sup>) gave micron-sized filaments as a result of the bundling/twisting of the nanofibers.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 7","pages":"Pages 1383-1386"},"PeriodicalIF":4.2000,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S135973452402737X","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/12/16 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Au25(SR)18 nanoclusters decorated with semifluorinated thiolate ligands (SFLs) self-assemble hierarchically depending on the charge state of the nanocluster component; the use of the anionic cluster ([Au25]−) resulted in the generation of nanofibers, whereas the neutral counterpart ([Au25]0) gave micron-sized filaments as a result of the bundling/twisting of the nanofibers.
期刊介绍：
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
