Steven P Nolan, Tommaso Ruggiero, Kristof Van Hecke, Catherine Cazin
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引用次数: 0
Abstract
The synthesis, isolation, and full characterization of a series of NHC-copper perfluoro-alkoxide complexes are reported. Their exceptional stability resides with the steric hindrance of the nonafluoro-tert-butyl alkoxide moiety, which exhibits a strong electron withdrawing effect. These new Cu(I) complexes are synthons that can permit the activation of acidic N–H and S–H bonds. The well-defined [Cu(IPr)(OC(CF3)3)] was investigated as a pre-catalyst in the Chan-Evans-Lam reaction.
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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