Boosting the luminescence performance of magneto-mechano-luminescence devices by leveraging self-generated electric potentials

IF 16.8 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Nano Energy Pub Date : 2025-02-01 DOI:10.1016/j.nanoen.2024.110593
Ji Yun Jung , Hyun Soo Kim , Chang Min Baek , Seungah Lee , Yuho Min , Hyun-Cheol Song , Jungho Ryu
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Abstract

The reported research on Mechano-luminescence (ML) has primarily focused on enhancing luminescence by optimizing mechanical energy for luminescence by employing various structural deformations of ML composites in response to mechanical stress. In contrast, this study demonstrates the innovative use of ambient magnetic fields to drive a lighting device without any external electrical source. This approach involves the simultaneous application of magnetically induced mechanical vibrations and a self-generated electric potential in the same periodic time. Our magnetically driven lighting device comprises a sheet-shaped ML composite consisting of ZnS:Cu particles embedded within a polydimethylsiloxane (PDMS) elastomer, along with a magnetically vibrating cantilever beam incorporating a 32-mode piezoelectric single crystal fiber composite (SFC). This structure forms a magneto-mechano-electric (MME) generator, capable of simultaneously applying mechanical stress and electrical potential to the ML composite under second harmonic bending vibration. Notably, the MME generator in second harmonic vibration mode responds to ambient magnetic field oscillations, inducing electric potential within the SFC. When the projection part of the MME generator contacts the ML composite, the induced electric potential supplies additional electrons to the ML material. This influx of electrons facilitates greater recombination within the ML composite, thereby enhancing luminescence efficiency. Our results indicate a 240 % improvement in luminescence efficiency when both mechanical and electrical energies are applied simultaneously compared to when only mechanical energy is utilized. When tested in a real-world environment at 60 Hz, the magnetically driven lighting device emits visible light without requiring any additional electrical power source.

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利用自生电势提高磁机械发光器件的发光性能
已报道的机械发光(ML)研究主要集中在通过优化机械能来增强发光,方法是利用 ML 复合材料的各种结构变形来响应机械应力。相比之下,本研究展示了如何创新性地利用环境磁场来驱动照明设备,而无需任何外部电源。这种方法涉及在同一周期内同时应用磁感应机械振动和自生电动势。我们的磁驱动照明设备由片状 ML 复合材料和磁振动悬臂梁组成,前者由嵌入聚二甲基硅氧烷(PDMS)弹性体中的 ZnS:Cu 颗粒组成,后者则包含 32 模压电单晶纤维复合材料(SFC)。这种结构形成了一个磁-机-电(MME)发生器,能够在二次谐波弯曲振动下同时向 ML 复合材料施加机械应力和电动势。值得注意的是,在二次谐波振动模式下,MME 发生器会对环境磁场振荡做出响应,从而在 SFC 内产生电动势。当 MME 发生器的投影部分接触到 ML 复合材料时,感应电动势会向 ML 材料提供额外的电子。电子的涌入促进了 ML 复合材料内部更大的重组,从而提高了发光效率。我们的研究结果表明,同时使用机械能和电能时,发光效率比只使用机械能时提高了 240%。在 60 赫兹的实际环境中进行测试时,磁驱动照明装置无需任何额外的电源即可发出可见光。
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来源期刊
Nano Energy
Nano Energy CHEMISTRY, PHYSICAL-NANOSCIENCE & NANOTECHNOLOGY
CiteScore
30.30
自引率
7.40%
发文量
1207
审稿时长
23 days
期刊介绍: Nano Energy is a multidisciplinary, rapid-publication forum of original peer-reviewed contributions on the science and engineering of nanomaterials and nanodevices used in all forms of energy harvesting, conversion, storage, utilization and policy. Through its mixture of articles, reviews, communications, research news, and information on key developments, Nano Energy provides a comprehensive coverage of this exciting and dynamic field which joins nanoscience and nanotechnology with energy science. The journal is relevant to all those who are interested in nanomaterials solutions to the energy problem. Nano Energy publishes original experimental and theoretical research on all aspects of energy-related research which utilizes nanomaterials and nanotechnology. Manuscripts of four types are considered: review articles which inform readers of the latest research and advances in energy science; rapid communications which feature exciting research breakthroughs in the field; full-length articles which report comprehensive research developments; and news and opinions which comment on topical issues or express views on the developments in related fields.
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