Responses of magnetic properties to heavy metals pollution recorded by sediments of Nanchang City reach of Ganjiang River, East China.

IF 3.2 3区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Environmental Geochemistry and Health Pub Date : 2024-12-18 DOI:10.1007/s10653-024-02320-9
Simeng Wang, Wen Li, Changsheng Ye, Yingqiu Gao, Yuqin Zhou
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Abstract

In this paper, sediment samples from the HT and QS profiles of the Ganjiang River are selected to represent the river reach that does not enter and entered the Nanchang City urban area, respectively. Environmental magnetism, granulometry, and heavy metal of these samples were analyzed to assess the relationship between magnetic properties and heavy metal. The results showed that the mean χ value of QS profile is 20.32 × 10-8m3/kg, which is higher than that in HT profile (3.80 × 10-8m3/kg), indicating the higher magnetic mineral concentrations. The relatively higher S-100mT, S-300mT, and lower χARM/χ, χARM/SIRM values of QS profile suggest the lower imperfect antiferromagnetic mineral proportion and the coarser magnetic minerals grains, respectively. The heavy metals (i.e., As, Cd, Sb, Cr, Cu, Zn, Pb) concentration of QS profile is markedly higher than that of HT profile. The PLI of QS profile ranges from 0.5 to 3.33, higher than that in HT profile (0.22 to 2.02), revealing the more serious pollution in urban areas and would be attributed to human activities. In QS and HT profile, the concentration-dependent magnetic parameters (e.g., χ, SIRM, HIRM) are significantly positively correlated with heavy metals and PLI. We also found that with a similar particle size composition, the sediment samples with higher pollution levels exhibit higher χ, SIRM, S-100mT, S-300mT, and lower χARM/χ, χARM/SIRM values, indicating the response of magnetic properties to heavy metal pollution. Magnetic parameters can be used as a heavy metal pollution indicator in the Ganjiang River.

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赣江南昌市段沉积物磁性对重金属污染的响应
本文选取了赣江 HT 剖面和 QS 剖面的沉积物样品,分别代表未进入和进入南昌市城区的河段。对这些样品的环境磁性、颗粒度和重金属进行了分析,以评估磁性与重金属之间的关系。结果表明,QS 剖面的平均 χ 值为 20.32 × 10-8m3/kg,高于 HT 剖面的平均 χ 值(3.80 × 10-8m3/kg),表明磁性矿物浓度较高。QS 剖面的 S-100mT、S-300mT 值相对较高,χARM/χ、χARM/SIRM 值相对较低,分别表明不完全反铁磁矿物比例较低和磁性矿物颗粒较粗。QS 剖面的重金属(即 As、Cd、Sb、Cr、Cu、Zn、Pb)浓度明显高于 HT 剖面。QS 剖面的 PLI 介于 0.5 至 3.33 之间,高于 HT 剖面的 PLI(0.22 至 2.02),表明城市地区的污染更为严重,可能与人类活动有关。在 QS 和 HT 剖面中,随浓度变化的磁参数(如 χ、SIRM、HIRM)与重金属和 PLI 显著正相关。我们还发现,在粒度组成相似的情况下,污染程度较高的沉积物样品表现出较高的χ、SIRM、S-100mT、S-300mT,以及较低的χARM/χ、χARM/SIRM 值,表明磁性能对重金属污染的响应。磁性参数可作为赣江重金属污染指标。
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来源期刊
Environmental Geochemistry and Health
Environmental Geochemistry and Health 环境科学-工程:环境
CiteScore
8.00
自引率
4.80%
发文量
279
审稿时长
4.2 months
期刊介绍: Environmental Geochemistry and Health publishes original research papers and review papers across the broad field of environmental geochemistry. Environmental geochemistry and health establishes and explains links between the natural or disturbed chemical composition of the earth’s surface and the health of plants, animals and people. Beneficial elements regulate or promote enzymatic and hormonal activity whereas other elements may be toxic. Bedrock geochemistry controls the composition of soil and hence that of water and vegetation. Environmental issues, such as pollution, arising from the extraction and use of mineral resources, are discussed. The effects of contaminants introduced into the earth’s geochemical systems are examined. Geochemical surveys of soil, water and plants show how major and trace elements are distributed geographically. Associated epidemiological studies reveal the possibility of causal links between the natural or disturbed geochemical environment and disease. Experimental research illuminates the nature or consequences of natural or disturbed geochemical processes. The journal particularly welcomes novel research linking environmental geochemistry and health issues on such topics as: heavy metals (including mercury), persistent organic pollutants (POPs), and mixed chemicals emitted through human activities, such as uncontrolled recycling of electronic-waste; waste recycling; surface-atmospheric interaction processes (natural and anthropogenic emissions, vertical transport, deposition, and physical-chemical interaction) of gases and aerosols; phytoremediation/restoration of contaminated sites; food contamination and safety; environmental effects of medicines; effects and toxicity of mixed pollutants; speciation of heavy metals/metalloids; effects of mining; disturbed geochemistry from human behavior, natural or man-made hazards; particle and nanoparticle toxicology; risk and the vulnerability of populations, etc.
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