Enhanced Photocatalytic Degradation of Reactive Dyes Under Visible Light Using ZnO/CdS/Co Nanocomposites: A Step Toward Advanced Environmental Remediation

IF 3.2 4区 化学 Q2 CHEMISTRY, ANALYTICAL Luminescence Pub Date : 2024-12-17 DOI:10.1002/bio.70053
Velumani Arun, Arumugam Priyadharsan, Santhanam Sivakumar, Rajendran Ranjith, Murni Handayani,  Muqoyyanah, Grace Gita Redhyka, Mohammad Ahmad Wadaan, Raja Mythili, Yosephin Dewiani Rahmayanti
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Abstract

In this study, ZnO, CdS, ZnO/CdS, and ZnO/CdS/Co nanostructures were successfully synthesized using a simple chemical precipitation method. The formation of these nanostructures was confirmed through x-ray diffraction (XRD), but their morphological properties were analyzed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Their optical properties were investigated using UV–visible diffuse reflectance spectroscopy (UV-DRS) and photoluminescence spectroscopy (PL). The photocatalytic activity of these materials was tested for the degradation of Reactive Blue 160 (RB 160) under visible light. It was observed that ZnO/CdS nanocomposites exhibited superior photocatalytic performance compared to pure ZnO. Furthermore, the inclusion of cobalt (Co) in the ZnO/CdS nanocomposites significantly enhanced this activity, likely due to improved visible light absorption. These findings suggest that ZnO/CdS/Co nanocomposites are promising candidates for efficient photocatalytic applications, particularly in environmental remediation under visible light.

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利用 ZnO/CdS/Co 纳米复合材料增强可见光下活性染料的光催化降解:迈向先进环境修复的一步。
在本研究中,采用简单的化学沉淀法成功合成了ZnO、CdS、ZnO/CdS和ZnO/CdS/Co纳米结构。通过x射线衍射(XRD)证实了这些纳米结构的形成,并通过扫描电子显微镜(SEM)和透射电子显微镜(TEM)分析了它们的形态特征。利用紫外-可见漫反射光谱(UV-DRS)和光致发光光谱(PL)研究了它们的光学性质。测试了这些材料在可见光下降解活性蓝160 (RB 160)的光催化活性。结果表明,与纯ZnO相比,ZnO/CdS纳米复合材料具有更好的光催化性能。此外,在ZnO/CdS纳米复合材料中加入钴(Co)显著增强了这种活性,可能是由于改善了可见光吸收。这些研究结果表明,ZnO/CdS/Co纳米复合材料具有良好的光催化应用前景,特别是在可见光下的环境修复中。
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来源期刊
Luminescence
Luminescence 生物-生化与分子生物学
CiteScore
5.10
自引率
13.80%
发文量
248
审稿时长
3.5 months
期刊介绍: Luminescence provides a forum for the publication of original scientific papers, short communications, technical notes and reviews on fundamental and applied aspects of all forms of luminescence, including bioluminescence, chemiluminescence, electrochemiluminescence, sonoluminescence, triboluminescence, fluorescence, time-resolved fluorescence and phosphorescence. Luminescence publishes papers on assays and analytical methods, instrumentation, mechanistic and synthetic studies, basic biology and chemistry. Luminescence also publishes details of forthcoming meetings, information on new products, and book reviews. A special feature of the Journal is surveys of the recent literature on selected topics in luminescence.
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