Metal-organic framework derived carbon-based composites for high-performance microwave absorption

IF 23.2 2区材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Advanced Composites and Hybrid Materials Pub Date : 2024-12-21 DOI:10.1007/s42114-024-01077-0

Shanshan Ran, Kai Sun, Minhui Zhao, Zhongyang Wang, Anoud Saud Alshammari, Mohamed H. Helal, Zeinhom M. El-Bahy, Yuan Yuan, Runhua Fan

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Abstract

There is an urgent need to develop high-performance absorbing materials to address the challenges of military stealth and daily electromagnetic pollution. Metal-organic frameworks (MOFs) are considered promising candidates due to their high porosity, large specific surface area, and tunable chemical structures. MOFs can be templates or precursors to transform into porous carbon, porous oxides, and metal-carbon composites at elevated temperatures. This paper reviews the synthesis strategies and recent advancements in MOF-derived carbon-based composites. The impact of various components and unique microstructures on these composites’ microwave absorption (MA) properties is analyzed. The discussion encompasses a range of composites, including porous carbon (PC) composites (such as metal/PC, metal oxide/PC, and metal/metal oxide/PC), as well as MOF derivatives combined with graphene, carbon nanotubes (CNTs), and carbon fibers (CFs). Additionally, the challenges and future directions regarding developing carbon-based microwave-absorbing materials (MAMs) derived from MOFs are discussed. This review aims to provide researchers with a comprehensive understanding of the design techniques pertinent to MOF-derived carbon-based composites in high-efficiency MAMs.

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来源期刊

Advanced Composites and Hybrid Materials Multiple-

CiteScore

26.00

自引率

21.40%

发文量

185

期刊介绍： Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.