Unveiling Biodiesel Production: Exploring Reaction Protocols, Catalysts, and Influential Factors

IF 6.2 3区 工程技术 Q1 ENGINEERING, CHEMICAL ChemBioEng Reviews Pub Date : 2024-11-11 DOI:10.1002/cben.202400028
Zahoor Ullah, Mohamad Azmi Bustam, Mohib Ullah,  Mamoon-Ur-Rashid, Amir Sada Khan, Syed Nasir Shah, Mansoor Ul Hassan Shah, Pervaiz Ahmad, Muhammad Sohail, Khalid Ali Khan
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Abstract

An environmentally responsible and sustainable replacement for finite fossil fuels is biodiesel. Because of its amazing qualities, biodiesel is becoming more and more popular as a renewable fuel around the globe. The many approaches, feedstocks, catalysts, comparison standards, reaction kinetics, final product analysis, and final product characterization of biodiesel are covered in this review article. Researchers have used a variety of techniques to produce biodiesel throughout history, with transesterification emerging as the most effective approach in more recent times. Numerous studies on biodiesel feedstock and catalysts to produce high biodiesel yields have been published; nevertheless, it should be highlighted that the type of feedstock must be considered while choosing a catalyst. The review paper highlights the significance of several parameters that are crucial to the manufacture of biodiesel, without which achieving a high yield would be challenging. The literature has also discussed the limitations and advantages of different catalysts, and scientists are currently working to identify the ideal catalyst within certain optimal parameters for the manufacture of biodiesel. Homogeneous reaction-based biodiesel synthesis has a number of drawbacks, though, such as water content, a laborious purification procedure, and a low tolerance for free fatty acids. To address these issues, scientists have started investigating heterogeneous reactions involving solid catalysts. A large pore network, a moderate-to-high density of strong acid sites, a hydrophobic surface, and the ability to control surface hydrophobicity to avoid deactivation are all desirable characteristics of an ideal solid catalyst. Ion exchange resins, sulfated oxides, heterogeneous base catalysts, boron group-based heterogeneous catalysts, alkaline earth metal oxides, mixed metal oxides, alkali metal oxides, heterogeneous catalysts derived from waste materials, and different approaches to biodiesel synthesis that employ enzymes, carbon-based heterogeneous catalysts, and ionic liquids as catalysts are among the categories of catalysts that can be used in the production of biodiesel. The finest benchmarks to compare the quality of biodiesel with European and American Society for Testing Material standards. For detailed characterization of the finished product, gas chromatography and nuclear magnetic resonance are the most effective methods.

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揭示生物柴油生产:探索反应方案、催化剂和影响因素
生物柴油是对环境负责且可持续的有限化石燃料替代品。由于其惊人的品质,生物柴油作为一种可再生燃料在全球越来越受欢迎。本文综述了生物柴油的制备方法、原料、催化剂、比较标准、反应动力学、最终产物分析和最终产物表征。纵观历史,研究人员已经使用了各种各样的技术来生产生物柴油,在最近的时代,酯交换反应成为最有效的方法。许多关于生物柴油原料和催化剂的研究已经发表,以生产高产量的生物柴油;然而,应该强调的是,在选择催化剂时必须考虑原料的类型。这篇综述论文强调了几个参数的重要性,这些参数对生物柴油的生产至关重要,没有这些参数,实现高产量将是具有挑战性的。文献还讨论了不同催化剂的局限性和优点,科学家们目前正在努力确定在某些最佳参数下制造生物柴油的理想催化剂。然而,基于均相反应的生物柴油合成有许多缺点,比如水含量高、纯化过程费力、对游离脂肪酸的耐受性低。为了解决这些问题,科学家们开始研究涉及固体催化剂的非均相反应。大的孔隙网络,中等至高密度的强酸位点,疏水表面,以及控制表面疏水性以避免失活的能力都是理想固体催化剂的理想特征。离子交换树脂、硫化氧化物、多相碱催化剂、硼基多相催化剂、碱土金属氧化物、混合金属氧化物、碱金属氧化物、从废物中提取的多相催化剂,以及以酶、碳基多相催化剂和离子液体为催化剂的不同生物柴油合成方法,都是可用于生物柴油生产的催化剂类别。最好的基准比较生物柴油的质量与欧洲和美国社会的测试材料标准。对于成品的详细表征,气相色谱和核磁共振是最有效的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
ChemBioEng Reviews
ChemBioEng Reviews Biochemistry, Genetics and Molecular Biology-Biochemistry
CiteScore
7.90
自引率
2.10%
发文量
45
期刊介绍: Launched in 2014, ChemBioEng Reviews is aimed to become a top-ranking journal publishing review articles offering information on significant developments and provide fundamental knowledge of important topics in the fields of chemical engineering and biotechnology. The journal supports academics and researchers in need for concise, easy to access information on specific topics. The articles cover all fields of (bio-) chemical engineering and technology, e.g.,
期刊最新文献
Cover Picture: ChemBioEng Reviews 6/2024 Table of Contents: ChemBioEng Reviews 6/2024 Masthead: ChemBioEng Reviews 1/2024 Unveiling Biodiesel Production: Exploring Reaction Protocols, Catalysts, and Influential Factors Review of 3D-Printed Titanium-Based Implants: Materials and Post-Processing
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