Beryllium carbonate: a model compound for highest capacity carbon sequestration chemistry†

IF 4.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY RSC Advances Pub Date : 2024-12-23 DOI:10.1039/D4RA07753A
Gad Licht, Kyle Hofstetter and Stuart Licht
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Abstract

Beryllium carbonate has the highest capacity to bind and release the greenhouse gas CO2 compared to amines, ionic liquids, CaCO3 or Li2CO3. The thermodynamic equilibrium for CO2 and BeO from BeCO3 is calculated. TGA of BeCO3 is used to determine the stepwise mechanism of its CO2 release, and the low melting point Li/Sr/BeCO3 is demonstrated.

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碳酸铍:最高容量碳封存化学的模型化合物
与胺、离子液体、CaCO3或Li2CO3相比,碳酸铍具有最高的结合和释放温室气体CO2的能力。计算了由BeCO3生成的CO2和BeO的热力学平衡。通过对BeCO3的热重热分析,确定了其CO2释放的分步机理,证明了Li/Sr/BeCO3的低熔点特性。
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来源期刊
RSC Advances
RSC Advances chemical sciences-
CiteScore
7.50
自引率
2.60%
发文量
3116
审稿时长
1.6 months
期刊介绍: An international, peer-reviewed journal covering all of the chemical sciences, including multidisciplinary and emerging areas. RSC Advances is a gold open access journal allowing researchers free access to research articles, and offering an affordable open access publishing option for authors around the world.
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