Solvents with different moisture levels: Critical impact factors on fluorescence-scintillation properties of liquid scintillators

IF 1.6 3区 工程技术 Q3 CHEMISTRY, INORGANIC & NUCLEAR Applied Radiation and Isotopes Pub Date : 2024-12-16 DOI:10.1016/j.apradiso.2024.111643
Yue Li , Yongqiang Zhang , Guoqiang Zhong , Wenjing Pu , Wei Lu , Weihua Wang
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Abstract

Liquid scintillator consists of an organic solvent and one or more scintillation solutes, which can emit light pulses after absorbing X- and γ-rays, or high-energy particles. It has the characteristics of strong neutron/γ-ray (n/γ) discrimination, short decay time, unlimited size and low cost, which plays an important role in high-sensitivity and large-scale radiation detection, especially in the construction and safe operation of nuclear facilities. However, the impact of solvent selection and moisture content on the fluorescence-scintillation properties of scintillators has not been adequately investigated in the literature. In this study, liquid scintillators consisting of scintillation solutes, 2, 5-diphenyl-oxazole and 1, 4-bis (5-phenyl-2-oxazolyl) benzene, were prepared with different moisture contents, which were determined using the Karl-Fischer method. The fluorescence emission spectra, scintillation sensitivity and n/γ discrimination were systematically characterized using various solvents with corresponding moisture contents. The results show that the scintillation count rate and n/γ discrimination reach their maximum values when employing p-xylene as the solvent and maintaining moisture content below 20 ppm. The theoretical calculation elucidates the performance degradation of liquid scintillators induced by moisture.
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不同水分水平的溶剂:液体闪烁体荧光闪烁性能的关键影响因素。
液体闪烁体由有机溶剂和一种或多种闪烁溶质组成,这些闪烁溶质吸收X射线和γ射线或高能粒子后可以发出光脉冲。它具有中子/γ射线(n/γ)鉴别力强、衰变时间短、尺寸不限、成本低等特点,在高灵敏度、大尺度辐射探测中,特别是在核设施建设和安全运行中发挥着重要作用。然而,溶剂选择和水分含量对闪烁体荧光闪烁性能的影响在文献中还没有得到充分的研究。本研究制备了由闪烁溶质2,5 -二苯基恶唑和1,4 -双(5-苯基-2-恶唑基)苯组成的不同含水量的液体闪烁体,并用卡尔-菲舍尔法测定了其含量。采用不同的溶剂和相应的含水率,系统地表征了荧光发射光谱、闪烁灵敏度和n/γ鉴别。结果表明,以对二甲苯为溶剂,保持水分含量在20 ppm以下时,闪烁计数率和n/γ辨别率达到最大值。理论计算说明了水分对液体闪烁体性能的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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文献相关原料
公司名称
产品信息
阿拉丁
1,4-dioxane
阿拉丁
THF
阿拉丁
p-xylene
阿拉丁
m-xylene
阿拉丁
o-xylene
来源期刊
Applied Radiation and Isotopes
Applied Radiation and Isotopes 工程技术-核科学技术
CiteScore
3.00
自引率
12.50%
发文量
406
审稿时长
13.5 months
期刊介绍: Applied Radiation and Isotopes provides a high quality medium for the publication of substantial, original and scientific and technological papers on the development and peaceful application of nuclear, radiation and radionuclide techniques in chemistry, physics, biochemistry, biology, medicine, security, engineering and in the earth, planetary and environmental sciences, all including dosimetry. Nuclear techniques are defined in the broadest sense and both experimental and theoretical papers are welcome. They include the development and use of α- and β-particles, X-rays and γ-rays, neutrons and other nuclear particles and radiations from all sources, including radionuclides, synchrotron sources, cyclotrons and reactors and from the natural environment. The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria. Papers dealing with radiation processing, i.e., where radiation is used to bring about a biological, chemical or physical change in a material, should be directed to our sister journal Radiation Physics and Chemistry.
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