Adsorptive immobilization of cadmium and lead using unmodified and modified biochar: A review of the advances, synthesis, efficiency and mechanisms

Abstract

Biochar is an environmentally friendly adsorbent material with excellent adsorption performance due to its extensive pore structure, large specific surface area, and numerous surface functional groups. It is commonly used to treat inorganic and organic pollutants. In recent years, with increasing focus on controlling soil pollution caused by heavy metals such as cadmium (Cd) and lead (Pb), the potential application of biochar has attracted much attention. This review used Citespace to quantitatively analyze the literature on the application of biochar from 2021 to 2024. It then explains the preparation techniques of unmodified and modified biochar and presents the physical and chemical properties and adsorption capacity of different biochar types for Cd and Pb. It also illustrates and compares the preparation process, modification methods, and adsorption mechanisms of biochar. Additionally, it evaluates the impacts of biochar application on heavy metal removal from rice, wheat, and corn, as well as their yields. This article contributes to the identification of the most effective materials and methods for biochar synthesis. It provides suggestions for remediation of soil heavy metal pollution and yield increase.