Synthesis of bishomocubanone derivatives via visible-light-induced intramolecular [2+2] cycloaddition reaction

IF 4.4 2区化学 Q2 CHEMISTRY, APPLIED Advanced Synthesis & Catalysis Pub Date : 2024-12-23 DOI:10.1002/adsc.202401345

Bingning Yan, Qingzhong Zhang, Yifei Ling, jiaxin liu, Jun Yang

引用次数: 0

Abstract

IIn this paper, a visible-light-induced intramolecular [2+2] cycloaddition has been revealed to synthesize the bishomocubanone derivatives in moderate to excellent yield under mild conditions. This method demonstrated a broad substrate scope and excellent functional-group tolerance, affording cubane precursors and a series of bishomocubanones. Meanwhile, a hundred-gram scale experiment of this method has been employed to synthesize cubane precursors with 98% yield.

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可见光诱导分子内[2+2]环加成反应合成双叔环醌衍生物

本文揭示了一种可见光诱导的分子内[2+2]环加成反应，在温和的条件下以中等至优异的产率合成了双叔环醌衍生物。该方法具有广泛的底物范围和良好的官能团耐受性，可制备出古方前体和一系列双古班酮。同时，在百克尺度实验中，以98%的收率合成了古本前驱体。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Advanced Synthesis & Catalysis 化学-应用化学

CiteScore

9.40

自引率

7.40%

发文量

447

审稿时长

1.8 months

期刊介绍： Advanced Synthesis & Catalysis (ASC) is the leading primary journal in organic, organometallic, and applied chemistry. The high impact of ASC can be attributed to the unique focus of the journal, which publishes exciting new results from academic and industrial labs on efficient, practical, and environmentally friendly organic synthesis. While homogeneous, heterogeneous, organic, and enzyme catalysis are key technologies to achieve green synthesis, significant contributions to the same goal by synthesis design, reaction techniques, flow chemistry, and continuous processing, multiphase catalysis, green solvents, catalyst immobilization, and recycling, separation science, and process development are also featured in ASC. The Aims and Scope can be found in the Notice to Authors or on the first page of the table of contents in every issue.