CuO nanoparticles-decorated femtosecond laser-irradiated WS2–WO3 heterojunctions to realize selective H2S gas sensor

IF 8 1区化学 Q1 CHEMISTRY, ANALYTICAL Sensors and Actuators B: Chemical Pub Date : 2024-12-25 DOI:10.1016/j.snb.2024.137167

Hyoungwon Park, Jonghyeok Kim, Sanghoon Ahn, Ali Mirzaei, Jae-Hun Kim, Changkyoo Park

{"title":"CuO nanoparticles-decorated femtosecond laser-irradiated WS2–WO3 heterojunctions to realize selective H2S gas sensor","authors":"Hyoungwon Park, Jonghyeok Kim, Sanghoon Ahn, Ali Mirzaei, Jae-Hun Kim, Changkyoo Park","doi":"10.1016/j.snb.2024.137167","DOIUrl":null,"url":null,"abstract":"Femtosecond (FS) laser irradiation is an easy and highly effective strategy for enhancing the sensing properties of resistive gas sensors. In this study, we applied this technique to WS2 nanosheets (NSs) to generate WS2–WO3 heterojunctions. Subsequently, they were decorated with CuO nanoparticles (NPs). Different characterization techniques demonstrated the formation of CuO-decorated WS2–WO3 heterojunction NSs with the desired morphology, phase, and chemical composition. Based on H2S gas-sensing studies, while non-irradiated WS2 sensors exhibited poor sensing performance, a combination of FS laser irradiation and CuO decoration led to significant performance improvement for H2S sensing in terms of response and selectivity. Enhanced performance is related to the formation of plenty of WS2–WO3 heterojunctions, oxygen vacancies, and the conversion of CuO to CuS with high metallic conductivity. We believe that the strategy used in this work can pave the way for the realization of low-temperature, sensitive, and selective H2S gas sensors.","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":"54 1","pages":""},"PeriodicalIF":8.0000,"publicationDate":"2024-12-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sensors and Actuators B: Chemical","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1016/j.snb.2024.137167","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}

引用次数: 0

Abstract

Femtosecond (FS) laser irradiation is an easy and highly effective strategy for enhancing the sensing properties of resistive gas sensors. In this study, we applied this technique to WS₂ nanosheets (NSs) to generate WS₂–WO₃ heterojunctions. Subsequently, they were decorated with CuO nanoparticles (NPs). Different characterization techniques demonstrated the formation of CuO-decorated WS₂–WO₃ heterojunction NSs with the desired morphology, phase, and chemical composition. Based on H₂S gas-sensing studies, while non-irradiated WS₂ sensors exhibited poor sensing performance, a combination of FS laser irradiation and CuO decoration led to significant performance improvement for H₂S sensing in terms of response and selectivity. Enhanced performance is related to the formation of plenty of WS₂–WO₃ heterojunctions, oxygen vacancies, and the conversion of CuO to CuS with high metallic conductivity. We believe that the strategy used in this work can pave the way for the realization of low-temperature, sensitive, and selective H₂S gas sensors.

Abstract Image

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

求助全文

约1分钟内获得全文去求助

来源期刊

Sensors and Actuators B: Chemical 工程技术-电化学

CiteScore

14.60

自引率

11.90%

发文量

1776

审稿时长

3.2 months

期刊介绍： Sensors & Actuators, B: Chemical is an international journal focused on the research and development of chemical transducers. It covers chemical sensors and biosensors, chemical actuators, and analytical microsystems. The journal is interdisciplinary, aiming to publish original works showcasing substantial advancements beyond the current state of the art in these fields, with practical applicability to solving meaningful analytical problems. Review articles are accepted by invitation from an Editor of the journal.