A green method of preparation of porous melamine formaldehyde resin without template in aqueous solution

IF 2.2 4区化学 Q3 CHEMISTRY, PHYSICAL Colloid and Polymer Science Pub Date : 2024-10-19 DOI:10.1007/s00396-024-05334-y

Huapeng Cui, Shengnan Li

{"title":"A green method of preparation of porous melamine formaldehyde resin without template in aqueous solution","authors":"Huapeng Cui, Shengnan Li","doi":"10.1007/s00396-024-05334-y","DOIUrl":null,"url":null,"abstract":"<div><p>Porous melamine formaldehyde resin (PMF) was synthesized without using template in aqueous solution with a green preparation method. Conditions such as formaldehyde/melamine, concentration, curing temperature, and time on pore parameters of synthesized porous melamine formaldehyde resin were investigated. The chemical property and pore structure of porous melamine formaldehyde resin were characterized by infrared spectroscopy, SEM, and BET. The results showed that the samples synthesized in solvent water had a surface higher than 490 m<sup>2</sup>/g, pore diameter of about 12.0 nm, and pore volume of about 1.2 cm<sup>3</sup>/g. The surface area and pore structure of porous melamine formaldehyde resin could be adjusted by changing the prepolymer concentration. Due to the large pore diameter and volume, it also adsorbed a great amount of Congo Red (CR), indicating an excellent adsorbent for large molecules. This investigation reveals that the -NH<sub>2</sub> and pore structure have great effects on the adsorption capacity of Congo Red dye of the as-synthesized melamine formaldehyde resin samples.</p><h3>Graphical Abstract</h3><p>The porous melamine formaldehyde resin without using template was synthesized by a green preparation method. The pore structure of the melamine formaldehyde resin was formed by nanoparticles accumulation. The surface area and pore structure of porous melamine formaldehyde resin could be adjusted by changing the prepolymer concentration. The adsorption capability of the porous melamine formaldehyde resin for Congo Red was up 720 mg/g.</p>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"303 1","pages":"111 - 118"},"PeriodicalIF":2.2000,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00396-024-05334-y.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloid and Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s00396-024-05334-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

Abstract

Porous melamine formaldehyde resin (PMF) was synthesized without using template in aqueous solution with a green preparation method. Conditions such as formaldehyde/melamine, concentration, curing temperature, and time on pore parameters of synthesized porous melamine formaldehyde resin were investigated. The chemical property and pore structure of porous melamine formaldehyde resin were characterized by infrared spectroscopy, SEM, and BET. The results showed that the samples synthesized in solvent water had a surface higher than 490 m²/g, pore diameter of about 12.0 nm, and pore volume of about 1.2 cm³/g. The surface area and pore structure of porous melamine formaldehyde resin could be adjusted by changing the prepolymer concentration. Due to the large pore diameter and volume, it also adsorbed a great amount of Congo Red (CR), indicating an excellent adsorbent for large molecules. This investigation reveals that the -NH₂ and pore structure have great effects on the adsorption capacity of Congo Red dye of the as-synthesized melamine formaldehyde resin samples.

Graphical Abstract

The porous melamine formaldehyde resin without using template was synthesized by a green preparation method. The pore structure of the melamine formaldehyde resin was formed by nanoparticles accumulation. The surface area and pore structure of porous melamine formaldehyde resin could be adjusted by changing the prepolymer concentration. The adsorption capability of the porous melamine formaldehyde resin for Congo Red was up 720 mg/g.

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

求助全文

约1分钟内获得全文去求助

来源期刊

Colloid and Polymer Science 化学-高分子科学

CiteScore

4.60

自引率

4.20%

发文量

111

审稿时长

2.2 months

期刊介绍： Colloid and Polymer Science - a leading international journal of longstanding tradition - is devoted to colloid and polymer science and its interdisciplinary interactions. As such, it responds to a demand which has lost none of its actuality as revealed in the trends of contemporary materials science.