Preparation and application of high strength, high transparency, and high impact resistance polyurethane elastomers by controlled cross-linking

IF 4.1 2区 化学 Q2 POLYMER SCIENCE Polymer Pub Date : 2025-01-22 DOI:10.1016/j.polymer.2024.128002
Siqi Zhan, Hongyan Liu, Yanyan Bo, Ruize Yuan, Yuting Zhang, Dongxiu Zhang, Huimin Yang, Xin Tian, Shiwei Wang, Mingyao Zhang
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Abstract

In recent years, polyurethane elastomer has been widespread used in automotive, aerospace, and other fields depending on its wide range of adjustable properties, both high elasticity of rubber and plastic rigidity. Its high transparency and high strength have attracted increasing attention, especially in the application of laminated safety glass. In this work, an aliphatic polyurethane film with superior dynamic impact resistance, optical and mechanical properties were successfully obtained by controlling the cross-linking agent and cross-linking degree. The effects of different cross-linking point structures on the structure and properties of aliphatic polyurethane were revealed. The optimal bonding strength and tensile strength can reach 1.7 MPa and 43 MPa, which are 170 % and 301 % higher than those of polyurethane, respectively. The transmittance of the aliphatic polyurethane can reach 80 %. Extremely superior impact resistance of the laminated safety glass based on the aliphatic polyurethane have been verified. The ultimate bearing capacity was 14 times of unmodified polyurethane. It will have huge application potential in the fields of aerospace, construction and automotive.

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可控交联制备高强度、高透明度、高抗冲击聚氨酯弹性体及其应用
近年来,聚氨酯弹性体凭借其广泛的可调性能,橡胶的高弹性和塑料的刚性,在汽车、航空航天等领域得到了广泛的应用。它的高透明度和高强度越来越受到人们的关注,特别是在夹层安全玻璃中的应用。通过控制交联剂和交联度,成功制备了具有优异动态抗冲击性能、光学性能和机械性能的脂肪族聚氨酯薄膜。揭示了不同交联点结构对脂肪族聚氨酯结构和性能的影响。最佳粘接强度和抗拉强度可达1.7 MPa和43 MPa,分别比聚氨酯提高170%和301%。脂族聚氨酯的透光率可达80%。经验证,脂肪族聚氨酯夹层安全玻璃具有极好的抗冲击性。极限承载力是未改性聚氨酯的14倍。在航空航天、建筑、汽车等领域具有巨大的应用潜力。
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文献相关原料
公司名称
产品信息
阿拉丁
N, N-Dimethylformamide
阿拉丁
N, N-Dimethylformamide (DMF)
阿拉丁
N, N-Dimethylformamide (DMF)
来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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