Surface-enhanced Raman scattering of R6G dimerization during self-healing of gel

IF 5.3 2区化学 Q1 CHEMISTRY, ANALYTICAL Microchimica Acta Pub Date : 2025-01-02 DOI:10.1007/s00604-024-06918-9

Yun Zhou, Minqiang Wang, Junnan Wang, Jindou Shi, Chen Zhang, Zheyuan Da, Youlong Xu, Yongqiang Ji, Nikolai V. Gaponenko, Arshad Saleem Bhatti

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Abstract

Traditional surface-enhanced Raman scattering (SERS) substrates seeking uniformity and reproducibility of the Raman signal often assume and require that hot spots remain consistently stable during Raman testing. Recently, the non-uniform accumulation in SERS sample pre-concentration strategies have inspired the direct use of self-healing noble metal aerogels (NMAs), as the sample pretreatment presented in this work, and uncovered more diverse Raman information of substances during the dynamic process of laser irradiation. Rare characteristic peaks such as 820 cm⁻¹ for R6G within a specific concentration range were observed, and potential processes including R6G dimerization and desorption were analyzed. These results provide insights into how to obtain more Raman information of diverse molecule forms under conventional conditions to distinguish the aggregation state, which turn the blinking of signals at low concentration or single molecule level into useful information.

Graphical Abstract

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来源期刊

Microchimica Acta 化学-分析化学

CiteScore

9.80

自引率

5.30%

发文量

410

审稿时长

2.7 months

期刊介绍： As a peer-reviewed journal for analytical sciences and technologies on the micro- and nanoscale, Microchimica Acta has established itself as a premier forum for truly novel approaches in chemical and biochemical analysis. Coverage includes methods and devices that provide expedient solutions to the most contemporary demands in this area. Examples are point-of-care technologies, wearable (bio)sensors, in-vivo-monitoring, micro/nanomotors and materials based on synthetic biology as well as biomedical imaging and targeting.