Cantilever-Enhanced Fiber-Optic Photoacoustic Spectrophone for Low-Pressure Gas Detection.

IF 6.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL Analytical Chemistry Pub Date : 2025-01-14 Epub Date: 2025-01-01 DOI:10.1021/acs.analchem.4c05422
Chenxi Li, Xiao Han, Min Guo, Hongchao Qi, Jingya Zhang, Xinyu Zhao, Ke Chen
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引用次数: 0

Abstract

A cantilever-enhanced fiber-optic photoacoustic (PA) spectrophone is reported for trace gas detection at a low-pressure environment. A cantilever-based fiber-optic Fabry-Perot (F-P) interferometer (FPI) is utilized for simultaneous measurement of air pressure and PA pressure. Since the cantilever resonance frequency follows air pressure linearly, the fundamental frequency intensity modulation (1f-IM) technique is applied to scan the frequency response of the solid PA signal from tube wall absorption for tracking the cantilever resonance frequency in real time. The second-harmonic wavelength modulation spectroscopy (2f-WMS) technique is used to measure the gas PA pressure wave at the cantilever resonance. According to the inverse restriction relationship of air pressure on the PA excitation and cantilever detection, the measured gas PA signal at the low-pressure environment is enhanced. The target gas concentration is corrected by the measured air pressure, which makes the spectrophone generally applicable under any pressure. The experimental results indicate that the normalized noise equivalent absorption (NNEA) coefficients of the spectrophone in the standard atmospheric pressure and the low-pressure environment of 60 kPa are 2.2 × 10-9 and 2.0 × 10-9 cm-1·W·Hz-1/2, respectively. 0.1 ppm acetylene (C2H2) can be detected at any air pressure. The detected maximum relative error of 10 ppm C2H2 gas under different pressures is less than ±9% and the error is reduced to less than ±2% when the concentration rises to 70 ppm. In the pressure range of 60-100 kPa, the cantilever-enhanced fiber-optic PA spectrophone has extremely high accuracy and pressure stability, covering the pressure range of most ground gas detection scenes.

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来源期刊
Analytical Chemistry
Analytical Chemistry 化学-分析化学
CiteScore
12.10
自引率
12.20%
发文量
1949
审稿时长
1.4 months
期刊介绍: Analytical Chemistry, a peer-reviewed research journal, focuses on disseminating new and original knowledge across all branches of analytical chemistry. Fundamental articles may explore general principles of chemical measurement science and need not directly address existing or potential analytical methodology. They can be entirely theoretical or report experimental results. Contributions may cover various phases of analytical operations, including sampling, bioanalysis, electrochemistry, mass spectrometry, microscale and nanoscale systems, environmental analysis, separations, spectroscopy, chemical reactions and selectivity, instrumentation, imaging, surface analysis, and data processing. Papers discussing known analytical methods should present a significant, original application of the method, a notable improvement, or results on an important analyte.
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