Enhancing the Electrocatalytic Oxidation of 5-Hydroxymethylfurfural (HMF) via Metallic Cobalt in Au–Co Nanoparticles

Abstract

The electrochemical oxidation of 5-hydroxymethylfurfural (HMF), derived from biomass, offers a sustainable route to valuable chemicals like 2,5-furandicarboxylic acid, used for the production of chemicals, polymers, and biofuels. Cobalt-based catalysts, especially Co₃O₄, have shown promise for HMF electrooxidation, but their poor conductivity limits their applicability. To address this issue, we synthesized and compared the catalytic activity of Au–Co branched and core–shell nanoparticles. We demonstrate that the branched Au–Co nanoparticles exhibit significantly higher electrocatalytic activity for HMF oxidation compared with the core–shell structure and commercial Co₃O₄. The enhanced performance of the branched structure arises from the high surface area and preservation of a metallic cobalt core in the branches, as demonstrated by the electron microscopy analysis. Electron impedance spectroscopy measurements show that the metallic branch core results in a lower charge transfer resistance for the branched nanoparticles compared with the cobalt oxide standard. These results suggest that preserving metallic cobalt in branched structures is key for efficient charge transfer, marking a significant advancement in the understanding of the use of Co catalysts for electrochemical HMF oxidation. This work emphasizes the role of the nanoparticle morphology in enhancing catalytic activity.