Circular Dichroism and Interlayer Exciton Hall Effect in Transition Metal Dichalcogenides Homobilayers

Abstract

In van der Waals (vdW) architectures of transition metal dichalcogenides (TMDCs), the coupling between interlayer exciton and quantum degrees of freedom opens unprecedented opportunities for excitonic physics. Taking the MoSe₂ homobilayer as representative, we identify that the interlayer registry defines the nature and dynamics of the lowest-energy interlayer exciton. The large layer polarization (P_n) is proved, which ensures the formation of layer-resolved interlayer excitons. In particular, sliding ferroelectric polarization couples to the dipole orientation of the interlayer exciton, thus achieving the long-sought electric control of excitonic states. In line with the phase winding of the Bloch states under C₃ rotational symmetry, we clarify the valley optical circular dichroism, enriching the exciton valleytronics. We also elucidate the Hall effect of the layer- and valley-polarized interlayer excitons, which advances our understanding of the spatial transport properties of the composite particles and provides new insights into the exciton-based applications.