Changhee Park , Seyun Gi , Seongkyeong Yoon , Seong Jung Kwon , Sunggi Lee
{"title":"The Giese reaction of alkyl bromides using amine carboxyboranes†","authors":"Changhee Park , Seyun Gi , Seongkyeong Yoon , Seong Jung Kwon , Sunggi Lee","doi":"10.1039/d4qo02325k","DOIUrl":null,"url":null,"abstract":"<div><div>Amine carboxyborane enabled efficient halogen atom transfer (XAT) with 1°, 2°, and 3° alkyl bromides, resulting in Giese addition products with various electron-deficient double bonds. Moreover, direct addition of several boryl radicals was also possible using several ligated carboxyboranes.</div></div>","PeriodicalId":94379,"journal":{"name":"Organic chemistry frontiers : an international journal of organic chemistry","volume":"12 6","pages":"Pages 1874-1878"},"PeriodicalIF":0.0000,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic chemistry frontiers : an international journal of organic chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2052412925000518","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Amine carboxyborane enabled efficient halogen atom transfer (XAT) with 1°, 2°, and 3° alkyl bromides, resulting in Giese addition products with various electron-deficient double bonds. Moreover, direct addition of several boryl radicals was also possible using several ligated carboxyboranes.
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