Effect of mechanical pre-treatment on the recovery potential of rare-earth elements and gold from discarded hard disc drives

IF 2.7 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Journal of Material Cycles and Waste Management Pub Date : 2024-11-04 DOI:10.1007/s10163-024-02108-0
Alireza Habibzadeh, Mehmet Ali Kucuker, Mertol Gökelma
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Abstract

The growing demand for rare-earth elements (REEs) and their limited availability have made REEs critical with high supply risk. E-waste, particularly waste electrical and electronic equipment (WEEE), offers a valuable secondary source. This study assesses the impact of mechanical pre-treatment on the recovery of REEs and gold from discarded hard disk drives (HDDs). We compared recovery efficiencies of REEs and Au using separation techniques, particle sizing, and chemical analyses between two pre-treatment methods: shredding and manual disassembly. Shredding, common in electronic waste processing, leads to oxidation and significant loss of critical raw materials (CRMs), while manual disassembly preserves clean, and non-oxidized NdFeB magnets for magnet-to-magnet recycling. Manually disassembled HDDs were directly analyzed to determine recyclable quantities of REEs and gold. Shredded HDDs underwent sieving, density, and magnetic separation, followed by demagnetization and chemical analysis. Results indicate shredding causes a 73.9% loss of REEs and a 43.8% loss of Au compared to manual disassembly, with increased oxidation due to finer particles. These findings suggest that while shredding is adequate for recovering ferrous and aluminum fractions, manual disassembly is essential for maximizing REE recovery.

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机械预处理对废弃硬盘中稀土元素和金回收潜力的影响
对稀土元素日益增长的需求及其有限的供应使得稀土元素具有高供应风险。电子垃圾,特别是废弃的电气和电子设备(WEEE),提供了宝贵的二次来源。本研究评估了机械预处理对从废弃硬盘驱动器(hdd)中回收稀土和金的影响。我们通过分离技术、粒度和化学分析比较了粉碎和手工拆解两种预处理方法的稀土和金的回收效率。粉碎在电子垃圾处理中很常见,会导致氧化和关键原材料(crm)的大量损失,而人工拆卸则保留了清洁的、未氧化的钕铁硼磁铁,用于磁体对磁体的回收。直接分析人工拆解的硬盘,以确定稀土和金的可回收量。粉碎的硬盘经过筛分、密度和磁选,然后是退磁和化学分析。结果表明,与手工拆解相比,粉碎导致稀土元素损失73.9%,金元素损失43.8%,并且由于颗粒更细而导致氧化增加。这些发现表明,虽然粉碎足以回收铁和铝馏分,但人工拆解对于最大限度地回收稀土元素至关重要。
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来源期刊
CiteScore
5.30
自引率
16.10%
发文量
205
审稿时长
4.8 months
期刊介绍: The Journal of Material Cycles and Waste Management has a twofold focus: research in technical, political, and environmental problems of material cycles and waste management; and information that contributes to the development of an interdisciplinary science of material cycles and waste management. Its aim is to develop solutions and prescriptions for material cycles. The journal publishes original articles, reviews, and invited papers from a wide range of disciplines related to material cycles and waste management. The journal is published in cooperation with the Japan Society of Material Cycles and Waste Management (JSMCWM) and the Korea Society of Waste Management (KSWM).
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