Fiber-Optic Photoacoustic Gas Microprobe Based on Linear Spot-Type Multipass Cell

IF 6.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL Analytical Chemistry Pub Date : 2025-01-09 DOI:10.1021/acs.analchem.4c05486
Heng Wang, Yufu Xu, Jingya Zhang, Xinyu Zhao, Zhaodong Zhang, Ke Chen
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Abstract

A linear spot-type multipass cell-enhanced fiber-optic photoacoustic gas microprobe is proposed. To further reduce the volume of the gas chamber and enhance the photoacoustic signal, we designed the cross section of the photoacoustic tube as a slit with a height of 10 mm and a width of 1.5 mm. The volume of the gas chamber is only 210 μL. Through theoretical analysis and multiphysical field simulation, the photoacoustic intensity of the slit cross section is more than 6 times that of traditional circular cross section. A cantilever beam is integrated into the photoacoustic microprobe and forms a Fabry–Perot (FP) interferometer with an optical fiber, achieving enhanced photoacoustic detection. By adjusting the angle of the collimator, the light passes through the photoacoustic cell 26 times, and 13 linear spots are formed on the reflecting surface. The photoacoustic signal with multiple linear reflections is 12.4 times that of a single reflection. The gas enters the sensor in a freely diffused manner, and the response time of the sensing system is 54 s. When the averaging time is 400 s, the detection limit of the designed sensor for acetylene gas reaches 1.5 ppb. The minimum detectable absorption coefficient (αmin) and the normalized noise equivalent absorption coefficient (NNEA) are 1.7 × 10–8 cm–1 and 1.9 × 10–9 Wcm–1/Hz1/2, respectively.

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基于线性点型多通单元的光纤光声气体微探头
提出了一种线性点型多通细胞增强光纤光声气体微探头。为了进一步减小气室的体积,增强光声信号,我们将光声管的横截面设计为高10 mm、宽1.5 mm的狭缝。毒气室的容积仅为210 μL。通过理论分析和多物理场模拟,狭缝截面的光声强度是传统圆形截面的6倍以上。将悬臂梁集成到光声微探头中,并与光纤形成法布里-珀罗(FP)干涉仪,实现增强的光声检测。通过调整准直器的角度,光通过光声电池26次,在反射面上形成13个线状光斑。多重线性反射的光声信号是单反射光声信号的12.4倍。气体以自由扩散的方式进入传感器,传感系统的响应时间为54s。当平均时间为400s时,所设计的传感器对乙炔气体的检出限达到1.5 ppb。最小可探测吸收系数αmin和归一化噪声等效吸收系数NNEA分别为1.7 × 10-8 cm-1和1.9 × 10-9 Wcm-1 /Hz1/2。
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来源期刊
Analytical Chemistry
Analytical Chemistry 化学-分析化学
CiteScore
12.10
自引率
12.20%
发文量
1949
审稿时长
1.4 months
期刊介绍: Analytical Chemistry, a peer-reviewed research journal, focuses on disseminating new and original knowledge across all branches of analytical chemistry. Fundamental articles may explore general principles of chemical measurement science and need not directly address existing or potential analytical methodology. They can be entirely theoretical or report experimental results. Contributions may cover various phases of analytical operations, including sampling, bioanalysis, electrochemistry, mass spectrometry, microscale and nanoscale systems, environmental analysis, separations, spectroscopy, chemical reactions and selectivity, instrumentation, imaging, surface analysis, and data processing. Papers discussing known analytical methods should present a significant, original application of the method, a notable improvement, or results on an important analyte.
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