Evaluating major element hydrogeochemistry and fluoride occurrence in groundwater of crystalline bedrock aquifers and associated controlling factors of Eumseong basin area, South Korea.
Jong Hyun Oh, Dong-Chan Koh, Hyo-Sik Seo, Nayeon Koh, Sung Won Kim
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引用次数: 0
Abstract
Long-term intake of high-fluoride water can cause fluorosis in bones and teeth or damage to organs. Fluoride in groundwater is primarily derived from reactions with rocks containing fluorine-related minerals, and fluoride concentrations are elevated in groundwater that has been reacting with these rocks for a long time. The purpose of this study is to investigate the origin and distribution of fluoride in groundwater and to assess the influence of various factors, including geology, on fluoride concentrations in groundwater. The Eumseong basin and surrounding areas were selected as the study area due to the diversity of geologic factors. 139 groundwater samples and 14 rock samples were collected, with groundwater samples subjected to field water quality measurements, chemical analysis, and statistical analysis, and rock samples subjected to microscopic observation and chemical analysis. Fluoride concentration in groundwater increased with well depth, and was highest in groundwater associated with granitic rocks rich in biotite. The fluoride concentration in groundwater showed a negative correlation with the distance to the fault, suggesting that deep groundwater may preferentially flow along fault zones in certain areas. In addition, high-fluoride groundwater had depleted water-stable isotope values, which is likely to be resulted from higher degree of water-rock interaction in groundwater recharged at higher elevations. Calcite precipitation in most groundwater appears to weaken fluorite solubility control on fluoride concentration. Multivariate statistical analysis revealed that water-rock interactions generally governed fluoride and major element concentrations, with high-fluoride groundwater clearly distinguished. These findings can aid in assessing fluoride occurrence in groundwater and managing water quality in areas with similar geological characteristics.
期刊介绍：
Environmental Geochemistry and Health publishes original research papers and review papers across the broad field of environmental geochemistry. Environmental geochemistry and health establishes and explains links between the natural or disturbed chemical composition of the earth’s surface and the health of plants, animals and people.
Beneficial elements regulate or promote enzymatic and hormonal activity whereas other elements may be toxic. Bedrock geochemistry controls the composition of soil and hence that of water and vegetation. Environmental issues, such as pollution, arising from the extraction and use of mineral resources, are discussed. The effects of contaminants introduced into the earth’s geochemical systems are examined. Geochemical surveys of soil, water and plants show how major and trace elements are distributed geographically. Associated epidemiological studies reveal the possibility of causal links between the natural or disturbed geochemical environment and disease. Experimental research illuminates the nature or consequences of natural or disturbed geochemical processes.
The journal particularly welcomes novel research linking environmental geochemistry and health issues on such topics as: heavy metals (including mercury), persistent organic pollutants (POPs), and mixed chemicals emitted through human activities, such as uncontrolled recycling of electronic-waste; waste recycling; surface-atmospheric interaction processes (natural and anthropogenic emissions, vertical transport, deposition, and physical-chemical interaction) of gases and aerosols; phytoremediation/restoration of contaminated sites; food contamination and safety; environmental effects of medicines; effects and toxicity of mixed pollutants; speciation of heavy metals/metalloids; effects of mining; disturbed geochemistry from human behavior, natural or man-made hazards; particle and nanoparticle toxicology; risk and the vulnerability of populations, etc.
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