Temperature Dependence of Optical Properties of MoS2 and WS2 Heterostructures Assessed by Spectroscopic Ellipsometry.

IF 4.3 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY Nanomaterials Pub Date : 2025-01-06 DOI:10.3390/nano15010076
Hoang Tung Nguyen, Van Long Le, Thi Mai Nguyen, Xuan Khuyen Bui, Thi Giang Nguyen, Nhat Linh Nguyen, Xuan Au Nguyen, Tae Jung Kim
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Abstract

We report the complex dielectric function ε = ε1 + 2 of MoS2/WS2 and WS2/MoS2 heterostructures and their constituent monolayers MoS2 and WS2 for an energy range from 1.5 to 6.0 eV and temperatures from 39 to 300 K. Comparisons between the optical properties of the heterostructures and their monolayers were conducted. Critical-point (CP) energies of the heterostructures were traced back to their origins in the monolayers. Low-temperature measurements confirmed the existence of only three excitonic CPs from 1.5 to 2.5 eV due to the overlap of trion B- of the MoS2 monolayer and exciton A0 of the WS2 monolayer. Due to the dielectric screening effect, most CPs exhibit red shifts in the heterostructures compared to their monolayer counterparts.

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用椭圆偏振光谱法研究MoS2和WS2异质结构光学性质的温度依赖性
本文报道了MoS2/WS2和WS2/MoS2异质结构及其组成单层MoS2和WS2在能量为1.5 ~ 6.0 eV,温度为39 ~ 300 K时的复介电函数ε = ε1 + 1 ε2。比较了异质结构及其单层的光学性质。异质结构的临界点(CP)能可以追溯到它们在单层中的起源。低温测量证实,由于MoS2单层的trion B-和WS2单层的激子A0重叠,在1.5 ~ 2.5 eV范围内仅存在3个激子CPs。由于介电屏蔽效应,与单层CPs相比,大多数CPs在异质结构中表现出红移。
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来源期刊
Nanomaterials
Nanomaterials NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.50
自引率
9.40%
发文量
3841
审稿时长
14.22 days
期刊介绍: Nanomaterials (ISSN 2076-4991) is an international and interdisciplinary scholarly open access journal. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. Thus, theoretical and experimental articles will be accepted, along with articles that deal with the synthesis and use of nanomaterials. Articles that synthesize information from multiple fields, and which place discoveries within a broader context, will be preferred. There is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental or methodical details, or both, must be provided for research articles. Computed data or files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Nanomaterials is dedicated to a high scientific standard. All manuscripts undergo a rigorous reviewing process and decisions are based on the recommendations of independent reviewers.
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