{"title":"Divergent Hydroelementation of Unsaturated C‐C Bonds Using 3d Transition Metal Based Catalysts","authors":"Soumitra Maity, Gargi Chakraborty","doi":"10.1002/adsc.202401239","DOIUrl":null,"url":null,"abstract":"Divergent hydroelementation reactions offer a cost‐effective synthetic protocol to prepare two or more products starting from same set of reactant molecules by altering one or more reaction parameters. This strategy is quite helpful in functionalizing unsaturated C‐C bonds into several value‐added chemical compounds by using various organic and metal‐based catalysts. In this regard, catalysts derived from 3d metals have come to the fore, providing an alternative to heavier transition metals and rare‐earth elements. In this review, we summarize and elucidate the recent developments of divergent hydroelementation of alkenes and alkynes using the first‐row transition metal complexes by categorizing them into three classes: (1) Catalyst and ligand‐controlled; (2) Reaction component‐controlled and (3) Substrate‐controlled. Given the importance of hydroelementation reactions, we hope this review will be helpful to the organic chemistry community.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"36 1","pages":""},"PeriodicalIF":4.4000,"publicationDate":"2025-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Synthesis & Catalysis","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/adsc.202401239","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
Divergent hydroelementation reactions offer a cost‐effective synthetic protocol to prepare two or more products starting from same set of reactant molecules by altering one or more reaction parameters. This strategy is quite helpful in functionalizing unsaturated C‐C bonds into several value‐added chemical compounds by using various organic and metal‐based catalysts. In this regard, catalysts derived from 3d metals have come to the fore, providing an alternative to heavier transition metals and rare‐earth elements. In this review, we summarize and elucidate the recent developments of divergent hydroelementation of alkenes and alkynes using the first‐row transition metal complexes by categorizing them into three classes: (1) Catalyst and ligand‐controlled; (2) Reaction component‐controlled and (3) Substrate‐controlled. Given the importance of hydroelementation reactions, we hope this review will be helpful to the organic chemistry community.
期刊介绍:
Advanced Synthesis & Catalysis (ASC) is the leading primary journal in organic, organometallic, and applied chemistry.
The high impact of ASC can be attributed to the unique focus of the journal, which publishes exciting new results from academic and industrial labs on efficient, practical, and environmentally friendly organic synthesis. While homogeneous, heterogeneous, organic, and enzyme catalysis are key technologies to achieve green synthesis, significant contributions to the same goal by synthesis design, reaction techniques, flow chemistry, and continuous processing, multiphase catalysis, green solvents, catalyst immobilization, and recycling, separation science, and process development are also featured in ASC. The Aims and Scope can be found in the Notice to Authors or on the first page of the table of contents in every issue.