Da Liu , Yue Wang , Jiarui Zhu , Xuewei Gu , Hao Yang , Yutian Xiong , Mingwang Shao , Qi Shao
{"title":"A two-dimensional amorphous iridium–cobalt oxide for an acidic oxygen evolution reaction†","authors":"Da Liu , Yue Wang , Jiarui Zhu , Xuewei Gu , Hao Yang , Yutian Xiong , Mingwang Shao , Qi Shao","doi":"10.1039/d4cc05227g","DOIUrl":null,"url":null,"abstract":"<div><div>A two-dimensional (2D) amorphous iridium cobalt oxide (Am-IrCo<sub><em>y</em></sub>O<sub><em>x</em></sub>) was prepared using the molten salt method. The optimal catalyst shows a low overpotential of 230 mV at 10 mA cm<sup>−2</sup> in 0.5 M H<sub>2</sub>SO<sub>4</sub>. DFT calculations show that the unsaturated Ir active sites on the surface are responsible for the excellent electrocatalytic performance. This work exhibits the advantages of 2D oxides and might find potential applications in other fields.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 10","pages":"Pages 2119-2122"},"PeriodicalIF":4.2000,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524028131","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/12/23 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A two-dimensional (2D) amorphous iridium cobalt oxide (Am-IrCoyOx) was prepared using the molten salt method. The optimal catalyst shows a low overpotential of 230 mV at 10 mA cm−2 in 0.5 M H2SO4. DFT calculations show that the unsaturated Ir active sites on the surface are responsible for the excellent electrocatalytic performance. This work exhibits the advantages of 2D oxides and might find potential applications in other fields.
采用熔盐法制备了一种二维(2D)无定形氧化铱钴(Am-ArCoyOx)。最佳催化剂在 0.5 M H2SO4 中 10 mA cm-2 的过电位为 230 mV。DFT 计算表明,表面的不饱和 Ir 活性位点是催化剂具有优异电催化性能的原因。这项工作展示了二维氧化物的优势,可能会在其他领域找到潜在的应用。
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.