Thermal management broadband-emitting device based on VO2 applied in the mid-infrared band

IF 3.3 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Dalton Transactions Pub Date : 2025-01-14 DOI:10.1039/D4DT03422H
Ying Zheng, Zhiyou Wang, Qianju Song, Zao Yi, Shubo Cheng and Yougen Yi
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Abstract

Mid-infrared thermal radiation has attracted attention due to its wide range of applications. Compared to the static process of thermal emission, if thermal radiation can be dynamically controlled, it would be more suitable for practical applications. Herein, we designed a controllable thermal emitter based on phase change materials. When the temperature changes from low to high, VO2 transitions from a dielectric state to a metallic state, and its imaginary part of the dielectric constant significantly increases, leading to differences in emission characteristics. At low temperatures, the device is in a low dielectric state and resonates weakly with incident light. The main emission comes from the bottom of the grating structure, with an emissivity of 0.21. At high temperatures, the structure is in a high dielectric state, and multiple resonance modes are excited within the structure, such as cavity resonance and surface plasmon resonance, which increases the emissivity to 0.95 and achieves effective heat dissipation. Given its superior thermal management capabilities and stability, this design holds promise for applications in thermal imaging, infrared communication, and energy-efficient devices.

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应用于中红外波段的基于VO2的热管理宽带发射装置
中红外热辐射因其广泛的应用而备受关注。与热发射的静态过程相比,热发射的动态控制更适合于实际应用。本文设计了一种基于相变材料的可控热发射器。当温度由低到高变化时,VO2由介电态转变为金属态,其介电常数虚部显著增大,导致发射特性的差异。在低温下,器件处于低介电状态,与入射光发生弱共振。主要发射来自光栅结构的底部,发射率为0.21。在高温下,结构处于高介电态,结构内部激发出腔共振和表面等离子体共振等多种共振模式,使发射率提高到0.95,实现了有效的散热。综上所述,利用相变材料VO2,该结构具有热管理能力和热稳定性,具有广阔的应用前景。
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来源期刊
Dalton Transactions
Dalton Transactions 化学-无机化学与核化学
CiteScore
6.60
自引率
7.50%
发文量
1832
审稿时长
1.5 months
期刊介绍: Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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